Controlled preparation of cobalt carbonate hydroxide@nickel aluminum layered double hydroxide core-shell heterostructure for advanced supercapacitors.

Herein, we report the rational fabrication of unique core-shell nanoclusters composed of cobalt carbonate hydroxide (Co-CH) @ nickel aluminum layered double hydroxide (NiAl-LDH) on a carbon cloth (CC) substrate using a two-step hydrothermal strategy. The one-dimensional (1D) Co-CH nanowires core-shell functions as a framework for the growth of two-dimensional (2D) NiAl-LDH nanosheets, leading to the formation of a hierarchically porous core-shell heterostructure. The presence of abundant heterointerfaces enhances electrical conductivity, reduces charge transfer resistance, and facilitates ion/electron transfer. Taking full advantage of its unique nanostructure and synergistic effect of two components, the as-prepared Co-CH@NiAl-LDH hybrid material illustrates a specific capacity of 1029.4 C/g (2058.9 mC cm) at 1 A g and good rate capability with a capacity retention of 68.5% at 20 A g. Additionally, the assembled Co-CH@NiAl-LDH//pine pollen-derived porous carbon (PPC) hybrid supercapacitor (HSC) delivers impressive energy and power densities of 66.2 Wh kg (0.27 Wh cm) and 17529.7 Wh kg (0.11 Wh cm), respectively. This device also achieves a superior capacity retention of 80.3% over 20,000 cycles. These findings prove the importance of engineering heterointerfaces in heterostructure for the promotion of energy storage performance.