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gCN-剥离BiFeO纳米复合材料的简便合成:一种用于降解水中各种纺织染料和抗生素的通用高效S型光催化剂

Facile Synthesis of gCN-Exfoliated BiFeO Nanocomposite: A Versatile and Efficient S-Scheme Photocatalyst for the Degradation of Various Textile Dyes and Antibiotics in Water.

作者信息

Upar Darshana Anand, Gogoi Debika, Das Manash R, Naik Bhanudas, Ghosh Narendra Nath

机构信息

Nano-Materials Lab, Department of Chemistry, Birla Institute of Technology and Science, Pilani K K Birla Goa Campus, Sancoale, Goa 403726, India.

Advanced Materials Group, Materials Sciences and Technology Division, CSIR-NEIST, Jorhat, Assam 785006, India.

出版信息

ACS Omega. 2023 Oct 6;8(41):38524-38538. doi: 10.1021/acsomega.3c05357. eCollection 2023 Oct 17.

Abstract

Water pollution engendered from textile dyes and antibiotics is a globally identified precarious concern that is causing dreadful risks to human health as well as aquatic lives. This predicament is escalating the quest to develop competent photocatalysts that can degrade these water pollutants under solar light irradiation. Herein, we report an efficient photocatalyst comprising a hierarchical structure by integrating the layered graphitic carbon nitride (gCN) with nanoflakes of exfoliated BiFeO. The coexistence of these two semiconducting nanomaterials leads to the formation of an S-scheme heterojunction. This nanocomposite demonstrated its excellent photocatalytic activity toward the degradation of several textile dyes (Yel CL2R, Levasol Yellow-CE, Levasol Red-GN, Navy Sol-R, Terq-CL5B) and various antibiotics (such as tetracycline hydrochloride (TCH), ciprofloxacin (CPX), sulfamethoxazole (SMX), and amoxicillin (AMX)) under the simulated solar light irradiation. As this photocatalyst exhibits its versatile activity toward the degradation of several commercial dyes as well as antibiotics, this work paves the path to develop a reasonable, eco-benign, and highly efficient photocatalyst that can be used in the practical approach to remediate environmental pollution.

摘要

纺织染料和抗生素造成的水污染是一个全球公认的严重问题,正在给人类健康和水生生物带来可怕风险。这种困境促使人们寻求开发出能在太阳光照射下降解这些水污染物的高效光催化剂。在此,我们报道了一种通过将层状石墨相氮化碳(gCN)与剥落的BiFeO纳米片集成而形成的具有分级结构的高效光催化剂。这两种半导体纳米材料的共存导致形成了S型异质结。这种纳米复合材料在模拟太阳光照射下对几种纺织染料(Yel CL2R、Levasol Yellow-CE、Levasol Red-GN、Navy Sol-R、Terq-CL5B)和各种抗生素(如盐酸四环素(TCH)、环丙沙星(CPX)、磺胺甲恶唑(SMX)和阿莫西林(AMX))的降解表现出优异的光催化活性。由于这种光催化剂对几种商业染料以及抗生素的降解都表现出多功能活性,这项工作为开发一种合理、环境友好且高效的光催化剂铺平了道路,该催化剂可用于实际的环境污染修复方法中。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4b3/10586259/111810ac92ad/ao3c05357_0006.jpg

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