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通过挤出和注塑成型从木质纤维素农业工业生物质中获得的聚合物材料。

Polymeric Materials Obtained by Extrusion and Injection Molding from Lignocellulosic Agroindustrial Biomass.

作者信息

Pacheco Ada, Evangelista-Osorio Arian, Muchaypiña-Flores Katherine Gabriela, Marzano-Barreda Luis Alejandro, Paredes-Concepción Perla, Palacin-Baldeón Heidy, Dos Santos Maicon Sérgio Nascimento, Tres Marcus Vinícius, Zabot Giovani Leone, Olivera-Montenegro Luis

机构信息

Bioprocesses and Biomass Conversion Research Group, Universidad San Ignacio de Loyola, La Molina 15024, Peru.

Grupo de Ciencia, Tecnología e Innovación en Alimentos, Universidad San Ignacio de Loyola, La Molina 15024, Peru.

出版信息

Polymers (Basel). 2023 Oct 10;15(20):4046. doi: 10.3390/polym15204046.

Abstract

This review presents the advances in polymeric materials achieved by extrusion and injection molding from lignocellulosic agroindustrial biomass. Biomass, which is derived from agricultural and industrial waste, is a renewable and abundant feedstock that contains mainly cellulose, hemicellulose, and lignin. To improve the properties and functions of polymeric materials, cellulose is subjected to a variety of modifications. The most common modifications are surface modification, grafting, chemical procedures, and molecule chemical grafting. Injection molding and extrusion technologies are crucial in shaping and manufacturing polymer composites, with precise control over the process and material selection. Furthermore, injection molding involves four phases: plasticization, injection, cooling, and ejection, with a focus on energy efficiency. Fundamental aspects of an injection molding machine, such as the motor, hopper, heating units, nozzle, and clamping unit, are discussed. Extrusion technology, commonly used as a preliminary step to injection molding, presents challenges regarding fiber reinforcement and stress accumulation, while lignin-based polymeric materials are challenging due to their hydrophobicity. The diverse applications of these biodegradable materials include automotive industries, construction, food packaging, and various consumer goods. Polymeric materials are positioned to offer even bigger contributions to sustainable and eco-friendly solutions in the future, as research and development continues.

摘要

本文综述了通过挤出和注塑成型从木质纤维素农业工业生物质中制备聚合物材料所取得的进展。生物质来源于农业和工业废弃物,是一种可再生且丰富的原料,主要包含纤维素、半纤维素和木质素。为改善聚合物材料的性能和功能,纤维素会进行多种改性。最常见的改性方法有表面改性、接枝、化学处理以及分子化学接枝。注塑成型和挤出技术在聚合物复合材料的成型和制造过程中至关重要,能够对工艺和材料选择进行精确控制。此外,注塑成型包括四个阶段:塑化、注射、冷却和顶出,重点在于能源效率。文中还讨论了注塑机的基本组成部分,如电机、料斗、加热单元、喷嘴和锁模单元。挤出技术通常作为注塑成型的预处理步骤,在纤维增强和应力积累方面存在挑战,而木质素基聚合物材料因其疏水性也具有挑战性。这些可生物降解材料的多样应用包括汽车工业、建筑、食品包装以及各类消费品。随着研发工作的持续推进,聚合物材料未来有望为可持续和环保解决方案做出更大贡献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45ee/10610583/2f8ec42f38e5/polymers-15-04046-g001.jpg

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