GENOCOV, Departament d'Enginyeria Química, Biològica i Ambiental, Escola d'Enginyeria, Universitat Autònoma de Barcelona, Bellaterra, Barcelona, Spain.
GENOCOV, Departament d'Enginyeria Química, Biològica i Ambiental, Escola d'Enginyeria, Universitat Autònoma de Barcelona, Bellaterra, Barcelona, Spain.
Sci Total Environ. 2024 Feb 20;912:168898. doi: 10.1016/j.scitotenv.2023.168898. Epub 2023 Nov 26.
Mainstream P-recovery can help wastewater treatment plants (WWTPs) to effectively maintain good enhanced biological phosphorus removal (EBPR) while helping to recover P. In this study, a pilot-scale anaerobic-anoxic-aerobic (AO) process was operated for simultaneous COD/N/P removal and P-recovery under different operational conditions. The operation with conventional extraction of waste activated sludge (WAS) from the aerobic reactor was compared to the mainstream P-recovery strategy of WAS extraction from the anaerobic reactor. Successful nutrient removal was obtained for both scenarios, but the anaerobic WAS extraction results improved polyphosphate accumulating organisms (PAOs) activity by increasing almost 27 % P concentration in the anaerobic reactor. WAS fermentation was also evaluated, showing that anaerobic WAS required only 3 days to reach a high P concentration, while the aerobic WAS fermentation required up to 7 days. The fermentation process increased the amount of soluble P available for precipitation from 24.4 % up to 51.6 % in the fermented anaerobic WAS scenario. Results obtained by precipitation modelling of these streams showed the limitations for struvite precipitation due to Ca interference and Mg and NH as limiting species. The optimum precipitation scenario showed that P-recovery could reach up to 51 % of the input P, being 90 % struvite.
主流磷回收可帮助废水处理厂(WWTP)在有效维持良好的增强生物除磷(EBPR)的同时回收磷。本研究在不同运行条件下,采用小规模厌氧-缺氧-好氧(AO)工艺进行 COD/N/P 去除和磷回收。将好氧反应器中传统的剩余活性污泥(WAS)提取与从厌氧反应器中提取主流磷回收策略进行了比较。两种方案均成功实现了营养物去除,但厌氧 WAS 提取可提高聚磷菌(PAOs)活性,使厌氧反应器中磷浓度增加近 27%。还评估了 WAS 发酵,结果表明厌氧 WAS 只需 3 天即可达到高磷浓度,而好氧 WAS 发酵则需要 7 天。发酵过程使可用于沉淀的可溶性磷量从发酵厌氧 WAS 方案中的 24.4%增加到 51.6%。对这些流进行沉淀模拟的结果表明,由于 Ca 干扰和 Mg 和 NH 作为限制物质,存在着鸟粪石沉淀的局限性。最佳沉淀方案表明,磷回收可达到输入磷的 51%,其中 90%为鸟粪石。