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线性不可逆热力学:热电学与生物标度律一瞥

Linear Irreversible Thermodynamics: A Glance at Thermoelectricity and the Biological Scaling Laws.

作者信息

Chimal-Eguia Juan Carlos, Páez-Hernández Ricardo Teodoro, Pacheco-Paez Juan Carlos, Ladino-Luna Delfino

机构信息

Laboratorio de Ciencias Matemáticas y Computacionales, Centro de Investigación en Computacion, Instituto Politecnico Nacional, Ciudad de Mexico 07738, Mexico.

Area de Fisica de Procesos Irreversibles, Departamento de Ciencias Basicas, Universidad Autonoma Metropolitana, U-Azcapotzalco, Av. San Pablo 180, Col. Reynosa, Ciudad de Mexico 02200, Mexico.

出版信息

Entropy (Basel). 2023 Nov 23;25(12):1575. doi: 10.3390/e25121575.

DOI:10.3390/e25121575
PMID:38136455
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10743106/
Abstract

This paper presents so-called thermoelectric generators (TEGs), which are considered thermal engines that transform heat into electricity using the Seebeck effect for this purpose. By using linear irreversible thermodynamics (LIT), it is possible to study the thermodynamic properties of TEGs for three different operating regimes: maximum power output (MPO), maximum ecological function (MEF) and maximum power efficiency (MPE). Then, by considering thermoelectricty, using the correspondence between the heat capacity of a solid and the metabolic rate, and taking the generation of energy by means of the metabolism of an organism as a process out of equilibrium, it is plausible to use linear irreversible thermodynamics (LIT) to obtain some interesting results in order to understand how metabolism is generated by a particle's released energy, which explains the empirically studied allometric laws.

摘要

本文介绍了所谓的热电发电机(TEG),它们被视为热机,为此利用塞贝克效应将热量转化为电能。通过使用线性不可逆热力学(LIT),可以研究TEG在三种不同运行状态下的热力学性质:最大功率输出(MPO)、最大生态功能(MEF)和最大功率效率(MPE)。然后,考虑到热电学,利用固体热容量与代谢率之间的对应关系,并将生物体通过新陈代谢产生能量视为一个非平衡过程,利用线性不可逆热力学(LIT)来获得一些有趣的结果,以便理解新陈代谢是如何由粒子释放的能量产生的,这解释了经实证研究的异速生长定律。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a14d/10743106/c12ff12c5f3d/entropy-25-01575-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a14d/10743106/93969797b758/entropy-25-01575-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a14d/10743106/5e546f28464f/entropy-25-01575-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a14d/10743106/c12ff12c5f3d/entropy-25-01575-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a14d/10743106/93969797b758/entropy-25-01575-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a14d/10743106/5e546f28464f/entropy-25-01575-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a14d/10743106/c12ff12c5f3d/entropy-25-01575-g003.jpg

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本文引用的文献

1
Optimization Criteria and Efficiency of a Thermoelectric Generator.热电发电机的优化标准与效率
Entropy (Basel). 2022 Dec 13;24(12):1812. doi: 10.3390/e24121812.
2
Recent Advances in Materials for Wearable Thermoelectric Generators and Biosensing Devices.可穿戴式热电发电机和生物传感设备材料的最新进展
Materials (Basel). 2022 Jun 18;15(12):4315. doi: 10.3390/ma15124315.
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Current trends in finite-time thermodynamics.有限时间热力学的当前趋势。
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First-order irreversible thermodynamic approach to a simple energy converter.简单能量转换器的一阶不可逆热力学方法。
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Complex thermoelectric materials.复杂热电材料
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The origin of allometric scaling laws in biology.生物学中异速生长比例定律的起源。
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Multi-level regulation and metabolic scaling.多层次调节与代谢比例关系
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Phys Rev E Stat Nonlin Soft Matter Phys. 2001 Mar;63(3 Pt 2):037102. doi: 10.1103/PhysRevE.63.037102. Epub 2001 Feb 21.
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Re-examination of the "3/4-law" of metabolism.新陈代谢“3/4定律”的重新审视。
J Theor Biol. 2001 Mar 7;209(1):9-27. doi: 10.1006/jtbi.2000.2238.