Mengeş Nurettin
Science and Technology Research and Application Center (BİTAM), Necmettin Erbakan University, Konya, Turkiye.
Department of Biomedical Engineering, Faculty of Engineering, Necmettin Erbakan University, Konya, Turkiye.
Turk J Chem. 2023 Sep 30;47(5):888-909. doi: 10.55730/1300-0527.3585. eCollection 2023.
Excited-state intramolecular proton transfer (ESIPT) is one of the most essential emission processes in most circumstances because of its dual emission band in most cases and its high Stokes shifts. These distinguishing properties make ESIPT-based probes more suitable for a variety of applications, including analyte sensors, solid-state sensing mechanisms, optical technologies, and biomarkers for endogenous or exogenous compounds in various settings. As a result, researchers around the world are working on ESIPT emissions and developing different scaffolds for various applications or industry demands. This field of study is rapidly expanding and there is a need for an up-to-date review of synthesis methodologies and applications. This paper provides the highlights of ESIPT-based heterocyclic scaffolds, synthesis strategies, and application scenarios in the literature from 2017 to 2023.
激发态分子内质子转移(ESIPT)在大多数情况下是最重要的发射过程之一,因为在大多数情况下它具有双发射带且斯托克斯位移较大。这些独特的性质使得基于ESIPT的探针更适用于各种应用,包括分析物传感器、固态传感机制、光学技术以及用于各种环境中内源性或外源性化合物的生物标志物。因此,世界各地的研究人员都在致力于ESIPT发射,并针对各种应用或行业需求开发不同的支架。这个研究领域正在迅速扩展,需要对合成方法和应用进行最新的综述。本文重点介绍了2017年至2023年文献中基于ESIPT的杂环支架、合成策略和应用场景。