Ramachandran P Veeraraghavan, Singh Aman, Walker Harry, Hamann Henry J
Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN 47907, USA.
Molecules. 2024 Jan 4;29(1):268. doi: 10.3390/molecules29010268.
Borane-pyridine acts as an efficient (5 mol%) liquid catalyst, providing improved solubility for the direct amidation of a wide range of aromatic and aliphatic carboxylic acids and amines to form secondary and tertiary carboxamides. Tolerance of potentially incompatible halo, nitro, and alkene functionalities has been demonstrated.
硼烷吡啶作为一种高效（5摩尔%）的液体催化剂，能提高多种芳香族和脂肪族羧酸与胺直接酰胺化反应的溶解性，以形成仲酰胺和叔酰胺。已证明该反应对可能不相容的卤素、硝基和烯烃官能团具有耐受性。
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