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在砂岩油藏中使用改性氧化锌纳米复合材料提高原油采收率。

Enhanced oil recovery by using modified ZnO nanocomposites in sandstone oil reservoirs.

作者信息

Ahmadi Yaser, Mansouri Mohsen, Pourafshary Peyman

机构信息

Chemical and Petroleum Engineering Department, Ilam University, P.O. Box 69315/516, Ilam, Iran.

School of Mining and Geosciences, Nazarbayev University, Astana, Kazakhstan.

出版信息

Sci Rep. 2024 Feb 2;14(1):2766. doi: 10.1038/s41598-024-53138-5.

DOI:10.1038/s41598-024-53138-5
PMID:38307963
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10837453/
Abstract

Recently, nanocomposites were employed to improve the extraction of oil in different reservoirs. Due to the unique characteristics of nanoparticles such as small size, efficient altering main mechanisms such as IFT, CA, and viscosity reduction, have received wide attention among researchers. This study investigated the application of a newly designed ZnO-cerium N-composite for EOR at reservoir conditions, and the performance was compared to the standalone ZnO nanoparticles. After performing the morphology of the N-composite, the effect of the N-composites on the wettability alteration, interfacial tension, viscosity, Zeta potential, pH, and density was studied at different N-composites concentrations at reservoir conditions. Based on the results of rock/fluid interactions at the static phase, an optimum concentration was chosen for performing dynamic core flooding experiments. At 100 ppm, the highest stability and the highest reduction in capillary force were observed. The presence of Ce in the structure of the N-composite changes the pore volume of ZnO-Ce compared to ZnO nanoparticles, which affects the surface charge. IFT (mN/m), CA (°), and zeta potential (mV) were (22.51, 40.83, and - 44.36), and (30.50, 50.21, and - 31.05) for ZnO-Ce and ZnO, respectively at 100 ppm. By application of the optimized nanofluid in an oil displacement study, RF in the presence of ZnO-Ce, and ZnO were 37.11% and 71.40%, respectively.

摘要

最近,纳米复合材料被用于提高不同油藏中的原油采收率。由于纳米颗粒具有诸如尺寸小等独特特性,其能够有效改变诸如界面张力、接触角和降低粘度等主要机理,因此受到了研究人员的广泛关注。本研究考察了一种新设计的氧化锌 - 铈纳米复合材料在油藏条件下用于提高采收率的应用情况,并将其性能与单独的氧化锌纳米颗粒进行了比较。在对纳米复合材料进行形态分析后,研究了在油藏条件下不同浓度的纳米复合材料对润湿性改变、界面张力、粘度、zeta电位、pH值和密度的影响。基于静态阶段岩石/流体相互作用的结果,选择了一个最佳浓度来进行动态岩心驱替实验。在100 ppm时,观察到最高的稳定性和最大程度的毛细管力降低。与氧化锌纳米颗粒相比,纳米复合材料结构中铈的存在改变了氧化锌 - 铈的孔隙体积,这影响了表面电荷。在100 ppm时,氧化锌 - 铈和氧化锌的界面张力(mN/m)、接触角(°)和zeta电位(mV)分别为(22.51、40.83和 - 44.36)以及(30.50、50.21和 - 31.05)。通过在驱油研究中应用优化后的纳米流体,氧化锌 - 铈和氧化锌存在时的采收率分别为37.11%和71.40%。

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