Increased solar-driven chemical transformations through surface-induced benzoperylene aggregation in dye-sensitized photoanodes.

The impact of benzo[ghi]perylenetriimide (BPTI) dye aggregation on the performance of photoelectrochemical devices was explored, through imide-substitution with either alkyl (BPTI-A, 2-ethylpropyl) or bulky aryl (BPTI-B, 2,6-diisopropylphenyl) moieties, to, respectively, enable or suppress aggregation. While both dyes demonstrated similar monomeric optoelectronic properties in solution, adsorption onto mesoporous SnO revealed different behavior, with BPTI-A forming aggregates via π-stacking and BPTI-B demonstrating reduced aggregation in the solid state. BPTI photoanodes were tested in dye-sensitized solar cells (DSSCs) before application to dye-sensitized photoelectrochemical cells (DSPECs) for Br production (a strong oxidant) coupled to H generation (a solar fuel). BPTI-A demonstrated a twofold higher dye loading of the SnO surface than BPTI-B, resulting in a fivefold enhancement to both photocurrent and Br production. The enhanced output of the photoelectrochemical systems (with respect to dye loading) was attributed to both J- and H- aggregation phenomena in BPTI-A photoanodes that lead to improved light harvesting. Our investigation provides a strategy to exploit self-assembly via aggregation to improve molecular light-harvesting and charge separation properties that can be directly applied to dye-sensitized photoelectrochemical devices.