Majdoub Mohammed, Sengottuvelu Dineshkumar, Nouranian Sasan, Al-Ostaz Ahmed
Center for Graphene Research and Innovation, University of Mississippi, University, MS 38677, United States.
Department of Chemical Engineering, University of Mississippi, University, MS 38677, United States.
ChemSusChem. 2024 Jul 8;17(13):e202301462. doi: 10.1002/cssc.202301462. Epub 2024 Mar 13.
Since their emergence in 2014, graphitic carbon nitride quantum dots (g-CN QDs) have attracted much interest from the scientific community due to their distinctive physicochemical features, including structural, morphological, electrochemical, and optoelectronic properties. Owing to their desirable characteristics, such as non-zero band gap, ability to be chemically functionalized or doped, possessing tunable properties, outstanding dispersibility in different media, and biocompatibility, g-CN QDs have shown promise for photocatalysis, energy devices, sensing, bioimaging, solar cells, optoelectronics, among other applications. As these fields are rapidly evolving, it is very strenuous to pinpoint the emerging challenges of the g-CN QDs development and application during the last decade, mainly due to the lack of critical reviews of the innovations in the g-CN QDs synthesis pathways and domains of application. Herein, an extensive survey is conducted on the g-CN QDs synthesis, characterization, and applications. Scenarios for the future development of g-CN QDs and their potential applications are highlighted and discussed in detail. The provided critical section suggests a myriad of opportunities for g-CN QDs, especially for their synthesis and functionalization, where a combination of eco-friendly/single step synthesis and chemical modification may be used to prepare g-CN QDs with, for example, enhanced photoluminescence and production yields.
自2014年出现以来,石墨相氮化碳量子点(g-CN QDs)因其独特的物理化学特性,包括结构、形态、电化学和光电性质,引起了科学界的广泛关注。由于其具有诸如非零带隙、可化学功能化或掺杂、具有可调性质、在不同介质中出色的分散性以及生物相容性等理想特性,g-CN QDs在光催化、能源器件、传感、生物成像、太阳能电池、光电子学等其他应用领域已展现出应用前景。随着这些领域的快速发展,要明确过去十年中g-CN QDs开发和应用中出现的挑战非常困难,主要原因是缺乏对g-CN QDs合成途径和应用领域创新的批判性综述。在此,对g-CN QDs的合成、表征和应用进行了广泛的调查。重点介绍并详细讨论了g-CN QDs未来发展的情景及其潜在应用。所提供的关键部分指出了g-CN QDs存在众多机会,特别是在其合成和功能化方面,其中可采用环保/单步合成与化学修饰相结合的方法来制备例如具有增强光致发光和产率的g-CN QDs。