Bain Erich D, Garboczi Edward J, Seppala Jonathan E, Parker Thomas C, Migler Kalman B
Materials and Manufacturing Sciences Division, U.S. Army Research Laboratory, Aberdeen Proving Ground, Aberdeen, MD 21005, USA.
Applied Chemicals and Materials Division, Material Measurement Laboratory, National Institute of Standards and Technology, Boulder, CO, USA.
Integr Mater Manuf Innov. 2019;8(3). doi: 10.1007/s40192-019-00146-3.
Laser sintering (LS) of polyamide 12 (PA12) is increasingly being adopted for industrial production of end-use parts, yet the complexity of this process coupled with the lack of organized, rigorous, publicly available process-structure-physical property datasets exposes manufacturers and customers to risks of unacceptably poor part quality and high costs. Although an extensive scientific literature has been developed to address some of these concerns, results are distributed among numerous reports based on different machines, materials, process parameters, and users. In this study, a single commercially important LS PA12 feedstock has been processed along four build dimensions of a modern production LS machine, characterized by a wide range of physical techniques, and compared to the same material formed by conventional melt processing. Results are discussed in the context of the literature, offering novel insights including distributions of particle size and shape, localization of semicrystalline phase changes due to LS processing, effect of chemical aging on melt viscosity, porosity orientation relative to LS build axes, and microstructural effects on tensile properties and failure mechanisms. The resulting datasets will be made publicly available to modelers and practitioners for the purpose of improving certifiability and repeatability of end-use parts manufactured by LS.
聚酰胺12(PA12)的激光烧结(LS)越来越多地被用于工业生产最终用途部件,但该工艺的复杂性,再加上缺乏系统、严格且公开可用的工艺 - 结构 - 物理性能数据集,使制造商和客户面临部件质量差得无法接受以及成本高昂的风险。尽管已经有大量科学文献来解决其中一些问题,但结果分散在众多基于不同机器、材料、工艺参数和用户的报告中。在本研究中,对一种具有商业重要性的单一LS PA12原料沿着一台现代生产LS机器的四个构建维度进行加工,采用多种物理技术进行表征,并与通过传统熔体加工形成的相同材料进行比较。结合文献对结果进行了讨论,提供了新的见解,包括粒度和形状分布、LS加工导致的半结晶相变的局部化、化学老化对熔体粘度的影响、孔隙率相对于LS构建轴的取向以及微观结构对拉伸性能和失效机制的影响。所得数据集将公开提供给建模人员和从业者,以提高通过LS制造的最终用途部件的可认证性和可重复性。