Rout Chandra Sekhar, Shinde Pratik V, Patra Abhinandan, Jeong Sang Mun
Centre for Nano and Material Sciences, Jain Global Campus, Jain (Deemed-to-be University), Kanakapura Road, Bangalore, Karnataka, 562112, India.
Department of Chemical Engineering, Chungbuk National University, Cheongju, Chungbuk, 28644, Republic of Korea.
Adv Sci (Weinh). 2024 Jun;11(21):e2308178. doi: 10.1002/advs.202308178. Epub 2024 Mar 25.
Metal borides have received a lot of attention recently as a potentially useful material for a wide range of applications. In particular, molybdenum-based borides and MBenes are of great significance, due to their remarkable properties like good electronic conductivity, considerable stability, high surface area, and environmental harmlessness. Therefore, in this article, the progress made in molybdenum-based borides and MBenes in recent years is reviewed. The first step in understanding these materials is to begin with an overview of their structural and electronic properties. Then synthetic technologies for the production of molybdenum borides, such as high-temperature/pressure methods, physical vapor deposition (PVD), chemical vapor deposition (CVD), element reaction route, molten salt-assisted, and selective etching methods are surveyed. Then, the critical performance of these materials in numerous applications like energy storage, catalysis, biosensors, biomedical devices, surface-enhanced Raman spectroscopy (SERS), and tribology and lubrication are summarized. The review concludes with an analysis of the current progress of these materials and provides perspectives for future research. Overall, this review will offer an insightful reference for the understanding molybdenum-based borides and their development in the future.
金属硼化物作为一种在广泛应用中具有潜在用途的材料,近年来受到了广泛关注。特别是钼基硼化物和硼烯,由于它们具有诸如良好的导电性、相当的稳定性、高表面积和环境无害性等显著特性,具有重要意义。因此,在本文中,我们综述了近年来钼基硼化物和硼烯所取得的进展。了解这些材料的第一步是概述它们的结构和电子性质。然后考察了用于制备钼硼化物的合成技术,如高温/高压法、物理气相沉积(PVD)、化学气相沉积(CVD)、元素反应路线、熔盐辅助法和选择性蚀刻法。接着,总结了这些材料在储能、催化、生物传感器、生物医学器件、表面增强拉曼光谱(SERS)以及摩擦学和润滑等众多应用中的关键性能。综述最后分析了这些材料的当前进展,并为未来研究提供了展望。总体而言,本综述将为理解钼基硼化物及其未来发展提供有见地的参考。