Khan Muhammad Soulaman, Ahsan Muhammad, Farrukh Sarah, Pervaiz Erum, Malik Abdul Qadeer
School of Chemical and Materials Engineering, National University of Sciences and Technology, Islamabad 44000, Pakistan.
Polymers (Basel). 2024 Mar 19;16(6):841. doi: 10.3390/polym16060841.
A number of coating techniques have been used to improve the processability of high explosives. These techniques are typically used for developing compositions, such as boosters and fillers. The most typically used technique is the "solvent-slurry coating". Several compositions of polymer-bonded explosives have been industrialized using this technique. The NUPC-6 polymer-bonded powder composition of hexahydro-1,3,5-trinitro-1,3,5-triazine is optimized using the solvent-slurry coating. It involved multiple processes, i.e., preparing a slurry of high explosives in an aqueous phase, dissolving the modified polymer binder in an organic solvent, maintaining both the solvent and slurry at controlled temperatures, introducing polymer binder solution and ingredients in the slurry, distilling the solvent, mixing contents homogeneously, filtering the polymer-coated hexahydro-1,3,5-trinitro-1,3,5-triazine composition, and drying in a vacuum oven. The phlegmatizing and hydrophobic agents enhance flowability and hydrophobicity. The mass flow rate, bulk density, tapped density, compressibility index, and Hausner ratio are determined to evaluate its flowability during filling operations. The results show that the composition is flowable using a filling funnel, with a 150 mm upper diameter, 25 mm flow diameter, and 136 mm total funnel height. The raw polymer binder was modified using diisooctylsebacate and SAE-10 oil. The additives in the composition enhance its flowability, and it might be used in underwater applications.
已经采用了多种包覆技术来改善高能炸药的加工性能。这些技术通常用于开发诸如传爆药和填料等成分。最常用的技术是“溶剂-淤浆包覆”。几种聚合物粘结炸药成分已通过该技术实现工业化。六氢-1,3,5-三硝基-1,3,5-三嗪的NUPC-6聚合物粘结粉末成分通过溶剂-淤浆包覆进行了优化。它涉及多个过程,即制备高能炸药在水相中的淤浆、将改性聚合物粘结剂溶解在有机溶剂中、将溶剂和淤浆都保持在受控温度、将聚合物粘结剂溶液和成分引入淤浆、蒸馏溶剂、将内容物均匀混合、过滤聚合物包覆的六氢-1,3,5-三硝基-1,3,5-三嗪成分,并在真空烘箱中干燥。钝感剂和疏水剂提高了流动性和疏水性。测定质量流率、堆积密度、振实密度、压缩性指数和哈斯纳比以评估其在填充操作期间的流动性。结果表明,使用上直径150毫米、流动直径25毫米和总漏斗高度136毫米的填充漏斗时,该成分具有流动性。原始聚合物粘结剂用癸二酸二异辛酯和SAE-10油进行了改性。该成分中的添加剂提高了其流动性,并且它可能用于水下应用。