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利用专利分析进行高效析氧催化剂的导向设计

Guided Design of Efficient Oxygen Evolution Catalysts Using Patent Analysis.

作者信息

Zhang Weiwei, Zhao Yongzhi, Xu Jiali, Jia Baorui, Zhang Wujun, Qin Mingli

机构信息

School of Economics and Management, University of Science and Technology Beijing, Beijing 100083, China.

Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China.

出版信息

ACS Omega. 2024 Apr 12;9(16):18160-18168. doi: 10.1021/acsomega.3c10195. eCollection 2024 Apr 23.

Abstract

The facile and rapid design of efficient oxygen evolution reaction (OER) catalysts holds paramount significance for energy conversion devices, such as water electrolyzers and fuel cells. Despite substantial progress in catalyst synthesis and performance exploration, the design and selection processes remain inefficient. In this context, we integrate patent analysis with catalyst design, leveraging the scholarly research functionalities within patent analyses to aid in the design and synthesis of a NiFeRu-carbon catalyst as a high-performance OER catalyst. The results demonstrate that the NiFeRu-Carbon catalyst with low Ru loading (0.3 wt %) exhibits an overpotential of only 219 mV at 10 mA cm under alkaline conditions, and after continuous operation for 200 h, the overpotential only attenuates by 15 mV. The incorporation of high-valence Ru dopants elevated the intrinsic activity of individual catalytic sites within NiFe-layered double hydroxides (LDHs). During the catalytic process, the partial dissolution of Ru might lead to the generation of numerous oxygen vacancies within NiFe- LDH, thereby enhancing the catalyst's activity and stability.

摘要

高效析氧反应(OER)催化剂的简便快速设计对于水电解槽和燃料电池等能量转换装置至关重要。尽管在催化剂合成和性能探索方面取得了重大进展,但设计和选择过程仍然效率低下。在此背景下,我们将专利分析与催化剂设计相结合,利用专利分析中的学术研究功能来辅助设计和合成一种作为高性能OER催化剂的NiFeRu-碳催化剂。结果表明,低Ru负载量(0.3 wt%)的NiFeRu-碳催化剂在碱性条件下10 mA cm时的过电位仅为219 mV,连续运行200 h后,过电位仅衰减15 mV。高价Ru掺杂剂的引入提高了NiFe层状双氢氧化物(LDHs)中单个催化位点的本征活性。在催化过程中,Ru的部分溶解可能导致NiFe-LDH中产生大量氧空位,从而提高催化剂的活性和稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b631/11044224/62c00019a3dd/ao3c10195_0001.jpg

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