Understanding charge transport and dielectric relaxation properties in lead-free CsZrCl nanoparticles.

In the exploration of perovskite materials devoid of lead and appropriate for capturing solar energy, a recent finding has surfaced concerning CsZrCl. This compound has attracted interest as a potential candidate, displaying advantageous optical and electrical features, coupled with remarkable durability under environmental stresses. This research outlines the effective production of non-toxic metal halide nanoparticles of CsZrCl using the gradual cooling technique. Thorough examinations have been conducted to explore the structural, optical, and dielectric traits. Over the frequency range of 10-10 Hz, the dielectric constant, loss factor, electric modulus, and electrical conductivity of CsZrCl exhibit a strong dependence on temperature. The Nyquist plot confirms the distinct contributions of grains and grain boundaries to the total impedance. In the high-frequency region, the dielectric constant tends to increase with temperature. In accordance with the modified Kohlrausch-Williams-Watts (KWW) equation, an asymmetric nature corresponding to the non-Debye type is observed in the electric modulus spectra at different temperatures. Furthermore, the imaginary part of the electric modulus spectrum shifts from the non-Debye type towards the Debye type with increasing temperature, despite not obtaining an exact Debye response. The frequency-dependent behavior of AC conductivity has been modeled using Joncher's universal law. The conduction mechanism within the CsZrCl compound is attributed to the small polaron tunneling model (NSPT). Furthermore, CsZrCl has the potential to function as an energy harvesting device due to its elevated dielectric constant combined with minimal dielectric loss.