Inaba Soma, Lu Weifang, Shima Ayaka, Ii Shiori, Takahashi Mizuki, Yamanaka Yuki, Hattori Yuta, Kubota Kosei, Huang Kai, Iwaya Motoaki, Takeuchi Tetsuya, Kamiyama Satoshi
Department of Materials Science and Engineering, Meijo University 1-501 Shiogamaguchi, Tenpaku-ku Nagoya 468-8502 Japan.
Fujian Key Laboratory of Semiconductor Materials and Applications, CI Center for OSED, Department of Physics, Xiamen University Xiamen 361005 China
Nanoscale Adv. 2024 Mar 27;6(9):2306-2318. doi: 10.1039/d3na01101a. eCollection 2024 Apr 30.
Significant attention has been directed toward core-shell GaInN/GaN multiple-quantum shell (MQS) nanowires (NWs) in the context of high-efficiency micro light-emitting diodes (micro-LEDs). These independent three-dimensional NWs offer the advantage of reducing the impact of sidewall etching regions. Furthermore, the emitting plane on the sidewalls demonstrates either nonpolar or semipolar orientation, while the dislocation density is exceptionally low. In this study, we assessed how changes in the NW morphology are affected by GaInN/GaN superlattice (SL) structures grown at varying growth temperatures, as well as control of the emission plane the p-GaN shell and emission sizes. The SL growth rate was enhanced at elevated growth temperatures, accompanied by the shrinkage of the (0001)-plane and expansion of the (11̄01)-plane on the NWs. The samples exhibited a higher light output when the SLs were grown at elevated temperatures compared to those grown with lower temperatures. A similar trend was observed for the samples with a gradual temperature transition during the growth. These findings indicate that the dimensions of the (0001)-plane can be controlled through SL growth, which in turn influences the emission properties of NW-LEDs. In addition, the emission properties of NW-LEDs with different growth time p-GaN shells and different emission sizes were investigated. Based on the NW-LED characteristics, it was revealed that the weak emission of the (0001)-plane was the dominant factor for the limited light output, and the most effective way to realize high efficiency devices is to suppress current injection into the apex or minimize the grown (0001)-plane region. Overall, it is one promising way to control the emission planes of NWs, which holds significant relevance for the potential application of NW-LEDs in the realm of micro-LEDs.
在高效微型发光二极管(micro-LED)的背景下,核壳结构的GaInN/GaN多量子壳(MQS)纳米线(NWs)受到了广泛关注。这些独立的三维纳米线具有减少侧壁蚀刻区域影响的优势。此外,侧壁上的发射平面呈现非极性或半极性取向,而位错密度极低。在本研究中,我们评估了在不同生长温度下生长的GaInN/GaN超晶格(SL)结构如何影响NW形态的变化,以及对发射平面、p-GaN壳层和发射尺寸的控制。在较高生长温度下,SL的生长速率提高,同时NWs上(0001)面收缩,(11̄01)面扩展。与在较低温度下生长的样品相比,在较高温度下生长SL时,样品表现出更高的光输出。在生长过程中温度逐渐变化的样品也观察到了类似的趋势。这些发现表明,可以通过SL生长来控制(0001)面的尺寸,这反过来又会影响NW-LED的发光特性。此外,还研究了具有不同生长时间p-GaN壳层和不同发射尺寸的NW-LED的发光特性。基于NW-LED的特性,发现(0001)面的弱发射是光输出受限的主要因素,实现高效器件的最有效方法是抑制电流注入到顶点或最小化生长的(0001)面区域。总体而言,控制NWs的发射平面是一种很有前景的方法,这与NW-LED在微型LED领域的潜在应用密切相关。