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热解工艺条件对苹果废弃物制备生物炭结构的影响

Impact of pyrolysis process conditions on the structure of biochar obtained from apple waste.

作者信息

Barszcz Wioletta, Łożyńska Monika, Molenda Jarosław

机构信息

Bioeconomy and Ecoinnovation Centre, Łukasiewicz Research Network - Institute for Sustainable Technologies, 26-600, Radom, Poland.

Faculty of Buildings Services, Hydro and Environmental Engineering, Warsaw University of Technology, 00-653, Warsaw, Poland.

出版信息

Sci Rep. 2024 May 7;14(1):10501. doi: 10.1038/s41598-024-61394-8.

Abstract

Biochar is an eco-friendly carbon material whose properties allow it to be used as a sorbent for wastewater treatment or soil remediation. The paper presents the results of research related to the pyrolysis process of apple waste after supercritical CO extraction with the simultaneous use of physical activation. The research assessed the influence of the temperature of the pyrolysis process and steam activation on the structural properties of the obtained biochar, i.e. specific surface, porous structure, and presence of functional groups. The results obtained confirmed that lower temperature pyrolysis produces biochar characterised by the presence of functional groups and ordered structure. On the other hand, high temperature pyrolysis with simultaneous steam activation determines microporosity and high values of the specific surface area. Taking into consideration pollutant sorption mechanisms (physical and chemical sorption), the obtained biochar materials can be used as sorbents in water and wastewater treatment.

摘要

生物炭是一种生态友好型碳材料,其特性使其能够用作废水处理或土壤修复的吸附剂。本文介绍了在超临界CO萃取后同时进行物理活化的条件下,苹果废料热解过程的相关研究结果。该研究评估了热解过程温度和蒸汽活化对所得生物炭结构特性的影响,即比表面积、多孔结构和官能团的存在情况。所得结果证实,较低温度热解产生的生物炭具有官能团且结构有序。另一方面,同时进行蒸汽活化的高温热解决定了微孔性和高比表面积值。考虑到污染物吸附机制(物理吸附和化学吸附),所得生物炭材料可用于水和废水处理中的吸附剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/358b/11076542/a4875a8b13ee/41598_2024_61394_Fig1a_HTML.jpg

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