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温度、氧气和蒸汽对一步法快速热解活化法制备的椰子壳活性炭粉末孔隙结构特征的影响。

Effects of temperature, oxygen and steam on pore structure characteristics of coconut husk activated carbon powders prepared by one-step rapid pyrolysis activation process.

机构信息

National Engineering Laboratory for Reducing Emissions from Coal Combustion, Engineering Research Center of Environmental Thermal Technology of Ministry of Education, Shandong Key Laboratory of Energy Carbon Reduction and Resource Utilization, School of Energy and Power Engineering, Shandong University, Jinan, Shandong 250061, China.

National Engineering Laboratory for Reducing Emissions from Coal Combustion, Engineering Research Center of Environmental Thermal Technology of Ministry of Education, Shandong Key Laboratory of Energy Carbon Reduction and Resource Utilization, School of Energy and Power Engineering, Shandong University, Jinan, Shandong 250061, China.

出版信息

Bioresour Technol. 2020 Aug;310:123413. doi: 10.1016/j.biortech.2020.123413. Epub 2020 Apr 18.

Abstract

Activated carbon powders made from coconut husk (CHCs) were prepared by one-step rapid pyrolysis activation process. Effects of temperature, oxygen and steam on the pore structure of CHCs were investigated. Results showed that high temperature, oxygen and steam all motivated the development of the CHCs pore structure. High temperature accelerated the evaporation of volatiles and led to more micropore structures. Oxygen promoted the development of both micropores and mesopores. CHCs' porosity separately presented a linear and a logarithmic growth with the increase of the preparation temperature and oxygen content. CHCs prepared under 1000 ℃ with activation agents of 6% oxygen and 20% steam exhibited the largest specific surface area and total pore volume of 415.85 m/g and 0.1748 cm/g. Steam can diffuse into the CHC matrix and enhance the formation of more mesopores. Steam over 20% would over-burn the substance and lead to the collapse of some pore structures.

摘要

椰壳活性炭粉末通过一步快速热解活化法制备。考察了温度、氧气和水蒸气对 CHC 孔结构的影响。结果表明,高温、氧气和水蒸气均促进了 CHC 孔结构的发展。高温加速了挥发物的蒸发,导致更多的微孔结构。氧气促进了微孔和中孔的发展。CHC 的孔隙率分别随制备温度和氧气含量的增加呈线性和对数增长。在 1000℃下,以 6%氧气和 20%水蒸气作为活化剂制备的 CHC 具有最大的比表面积和总孔体积,分别为 415.85 m/g 和 0.1748 cm/g。水蒸气可以扩散到 CHC 基质中,从而增强更多中孔的形成。水蒸气超过 20%会过度燃烧物质,导致一些孔结构的坍塌。

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