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对当前用于电池的锂和锌的可用性的批判性讨论。

A critical discussion of the current availability of lithium and zinc for use in batteries.

作者信息

Innocenti Alessandro, Bresser Dominic, Garche Jürgen, Passerini Stefano

机构信息

Helmholtz Institute Ulm (HIU), Helmholtzstrasse 11, 89081, Ulm, Germany.

Karlsruhe Institute of Technology (KIT), P.O. Box 3640, 76021, Karlsruhe, Germany.

出版信息

Nat Commun. 2024 May 14;15(1):4068. doi: 10.1038/s41467-024-48368-0.

DOI:10.1038/s41467-024-48368-0
PMID:38744859
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11094038/
Abstract

In the literature on zinc-based batteries, it is often highlighted that zinc offers significant advantages over lithium due to its abundance, affordability, and accessibility. Additionally, aqueous rechargeable zinc batteries are promoted as a sustainable and cost-effective alternative to lithium-ion batteries, especially for renewable energy storage. The aim of this Comment is to provide a perspective on these statements, elucidating their foundations and implications and giving a quick but comprehensive background to authors and readers that deal with this topic, focusing specifically on batteries with zinc ions shuttling reversibly between the metallic negative electrode and the insertion-type positive electrode.

摘要

在关于锌基电池的文献中,人们经常强调,由于锌储量丰富、价格低廉且易于获取,与锂相比具有显著优势。此外,水系可充电锌电池被推崇为锂离子电池的一种可持续且经济高效的替代品,特别是在可再生能源存储方面。本评论的目的是对这些观点提供一种视角,阐明其依据和影响,并为处理该主题的作者和读者提供一个快速而全面的背景知识,特别聚焦于锌离子在金属负极和嵌入型正极之间可逆穿梭的电池。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e783/11094038/a4be3ef4daea/41467_2024_48368_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e783/11094038/ab2e74dadb3a/41467_2024_48368_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e783/11094038/a4be3ef4daea/41467_2024_48368_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e783/11094038/ab2e74dadb3a/41467_2024_48368_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e783/11094038/a4be3ef4daea/41467_2024_48368_Fig2_HTML.jpg

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The role of concentration in electrolyte solutions for non-aqueous lithium-based batteries.
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The Impact of Aluminum Doping on the Performance of MgVO Spinel Cathodes for High-Rate Zinc-Ion Energy Storage.铝掺杂对用于高速锌离子储能的MgVO尖晶石阴极性能的影响
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