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用电凝聚和集成膜处理电镀废水。

Treatment of electroplating wastewater using electrocoagulation and integrated membrane.

机构信息

The Institution of Energy and Architecture, Xi'an Aeronautical Institute, Xi'an 710077, China E-mail:

Ankang Agricultural Product Quality and Safety Inspection and Monitoring Center, Ankang 725000, China.

出版信息

Water Sci Technol. 2024 May;89(9):2538-2557. doi: 10.2166/wst.2024.136. Epub 2024 Apr 26.

DOI:10.2166/wst.2024.136
PMID:38747966
Abstract

Electroplating wastewater contains heavy metal ions and organic matter. These contaminants not only endanger the environment but also pose risks to human health. Despite the development of various treatment processes such as chemical precipitation MBR, electrocoagulation (EC) ceramic membrane (CM), coagulation ultrafiltration (UF) reverse osmosis (RO), and CM RO. These methods are only effective for low concentrations of heavy metals and struggle with high concentrations. To address the challenge of treating electroplating wastewater with high heavy metal content, this study focuses on the wastewater from Dongfang Aviation Machinery Processing Plant. It introduces an EC and integrated membrane (IM) treatment process for electroplating wastewater. The IM comprises microfiltration (MF) membrane, nanofiltration (NF) membrane, and RO membrane. Results indicated that under specific conditions, such as a pH of 8, current density of 5 A/dm, electrode plate spacing of 2 cm, 35 min of electrolysis time, and influent pH of 10 for the IM, removal rates of Zn, Cu, Ni, and TCr in the wastewater exceeded 99%. The removal rates of chemical oxygen demand (COD), suspended solids (SS), total phosphorus (TP), total nitrogen (TN), and petroleum in wastewater exceed 97%. Following a continuous cleaning process, the membrane flux can consistently recover to over 94.3%.

摘要

电镀废水中含有重金属离子和有机物。这些污染物不仅危害环境,还对人类健康构成威胁。尽管已经开发出各种处理工艺,如化学沉淀、MBR、电絮凝(EC)陶瓷膜(CM)、混凝超滤(UF)反渗透(RO)和 CM-RO 等,但这些方法仅对低浓度重金属有效,而对于高浓度重金属则难以处理。为了解决含高浓度重金属的电镀废水处理问题,本研究以东方航空机械加工厂的电镀废水为研究对象,采用电絮凝和集成膜(IM)处理电镀废水。IM 由微滤(MF)膜、纳滤(NF)膜和反渗透(RO)膜组成。结果表明,在特定条件下,如 pH 值为 8、电流密度为 5 A/dm、电极板间距为 2 cm、电解时间为 35 min 和 IM 进水 pH 值为 10 时,废水中 Zn、Cu、Ni 和 TCr 的去除率均超过 99%。COD、SS、TP、TN 和石油在废水中的去除率均超过 97%。经过连续清洗过程,膜通量可始终恢复至 94.3%以上。

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