• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

拯救锌负极-电解质界面：机制、理论模拟与表征

Rescuing zinc anode-electrolyte interface: mechanisms, theoretical simulations and characterizations.

作者信息

Liu Zhenjie, Zhang Xiaofeng, Liu Zhiming, Jiang Yue, Wu Dianlun, Huang Yang, Hu Zhe

机构信息

Guangdong Provincial Key Laboratory of New Energy Materials Service Safety, College of Materials Science and Engineering, Shenzhen University Shenzhen 518055 Guangdong P. R. China

The Hong Kong University of Science and Technology (Guangzhou), Advanced Materials Thrust Nansha Guangzhou 511400 Guangdong P. R. China

出版信息

Chem Sci. 2024 Apr 8;15(19):7010-7033. doi: 10.1039/d4sc00711e. eCollection 2024 May 15.

DOI:10.1039/d4sc00711e
PMID:38756795
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11095385/
Abstract

The research interest in aqueous zinc-ion batteries (AZIBs) has been surging due to the advantages of safety, abundance, and high electrochemical performance. However, some technique issues, such as dendrites, hydrogen evolution reaction, and corrosion, severely prohibit the development of AZIBs in practical utilizations. The underlying mechanisms regarding electrochemical performance deterioration and structure degradation are too complex to understand, especially when it comes to zinc metal anode-electrolyte interface. Recently, theoretical simulations and characterizations have played a crucial role in AZIBs and are exploited to guide the research on electrolyte engineering and solid electrolyte interphase. Herein, we present a comprehensive review of the current state of the fundamental mechanisms involved in the zinc plating/stripping process and underscore the importance of theoretical simulations and characterizations in mechanism research. Finally, we summarize the challenges and opportunities for AZIBs in practical applications, especially as a stationary energy storage and conversion device in a smart grid.

摘要

由于具有安全、储量丰富和高电化学性能等优点，水系锌离子电池（AZIBs）的研究热度一直在飙升。然而，一些技术问题，如枝晶、析氢反应和腐蚀等，严重阻碍了AZIBs在实际应用中的发展。电化学性能恶化和结构退化的潜在机制过于复杂，难以理解，尤其是涉及锌金属阳极-电解质界面时。最近，理论模拟和表征在AZIBs研究中发挥了关键作用，并被用于指导电解质工程和固体电解质界面的研究。在此，我们对锌电镀/剥离过程中涉及的基本机制的当前状态进行了全面综述，并强调了理论模拟和表征在机制研究中的重要性。最后，我们总结了AZIBs在实际应用中的挑战和机遇，特别是作为智能电网中的固定储能和转换装置。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/3186eacf2f09/d4sc00711e-p3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/1bd0c21e784a/d4sc00711e-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/62ef63101a93/d4sc00711e-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/1a4008a3dd22/d4sc00711e-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/8baa5e3c40c6/d4sc00711e-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/5c001eb83437/d4sc00711e-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/1fa903e7e307/d4sc00711e-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/a17c911de992/d4sc00711e-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/c78f54ff3e97/d4sc00711e-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/b63072d84da9/d4sc00711e-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/f3592f2ce37f/d4sc00711e-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/8f3b78291299/d4sc00711e-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/61535f001aea/d4sc00711e-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/4d8b5bd24491/d4sc00711e-p2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/3186eacf2f09/d4sc00711e-p3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/1bd0c21e784a/d4sc00711e-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/62ef63101a93/d4sc00711e-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/1a4008a3dd22/d4sc00711e-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/8baa5e3c40c6/d4sc00711e-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/5c001eb83437/d4sc00711e-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/1fa903e7e307/d4sc00711e-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/a17c911de992/d4sc00711e-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/c78f54ff3e97/d4sc00711e-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/b63072d84da9/d4sc00711e-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/f3592f2ce37f/d4sc00711e-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/8f3b78291299/d4sc00711e-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/61535f001aea/d4sc00711e-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/4d8b5bd24491/d4sc00711e-p2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b4f7/11095385/3186eacf2f09/d4sc00711e-p3.jpg

相似文献

1
Rescuing zinc anode-electrolyte interface: mechanisms, theoretical simulations and characterizations.拯救锌负极-电解质界面：机制、理论模拟与表征
Chem Sci. 2024 Apr 8;15(19):7010-7033. doi: 10.1039/d4sc00711e. eCollection 2024 May 15.
2
Towards Superior Aqueous Zinc-Ion Batteries: The Insights of Artificial Protective Interfaces.迈向高性能水系锌离子电池：人工保护界面的见解
ChemSusChem. 2024 Oct 21;17(20):e202301942. doi: 10.1002/cssc.202301942. Epub 2024 Jun 18.
3
Recent Progress in Aqueous Zinc-ion Batteries at High Zinc Utilization.高锌利用率水系锌离子电池的最新进展
ChemSusChem. 2025 Jan 2;18(1):e202401166. doi: 10.1002/cssc.202401166. Epub 2024 Sep 6.
4
Cyclohexanedodecol-Assisted Interfacial Engineering for Robust and High-Performance Zinc Metal Anode.环己烷十二醇辅助的界面工程用于坚固且高性能的锌金属负极
Nanomicro Lett. 2022 Apr 19;14(1):110. doi: 10.1007/s40820-022-00846-0.
5
Revitalizing zinc-ion batteries with advanced zinc anode design.先进锌阳极设计助力锌离子电池焕发新生。
Nanoscale Horiz. 2022 Dec 20;8(1):29-54. doi: 10.1039/d2nh00354f.
6
Toward Long-Life Aqueous Zinc Ion Batteries by Constructing Stable Zinc Anodes.通过构建稳定的锌负极迈向长寿命水系锌离子电池。
Chem Rec. 2022 Oct;22(10):e202200088. doi: 10.1002/tcr.202200088. Epub 2022 Jun 2.
7
Inhibiting corrosion and side reactions of zinc metal anode by nano-CaSiOcoating towards high-performance aqueous zinc-ion batteries.纳米 CaSiO 涂层抑制锌金属阳极的腐蚀和副反应，实现高性能水系锌离子电池。
Nanotechnology. 2022 Dec 7;34(8). doi: 10.1088/1361-6528/aca1cd.
8
Hybrid Organic/Inorganic Interphase for Stabilizing a Zinc Metal Anode in a Mild Aqueous Electrolyte.用于在温和水性电解质中稳定锌金属负极的有机/无机混合界面
ACS Appl Mater Interfaces. 2022 Nov 2;14(43):48675-48681. doi: 10.1021/acsami.2c13645. Epub 2022 Oct 18.
9
A Synergistic Strategy of Organic Molecules Introduced a High Zn Flux Solid Electrolyte Interphase for Stable Aqueous Zinc-Ion Batteries.一种有机分子协同策略引入高锌通量固体电解质界面用于稳定水系锌离子电池
ACS Appl Mater Interfaces. 2022 Oct 26;14(42):48081-48090. doi: 10.1021/acsami.2c12118. Epub 2022 Oct 12.
10
Advancing Zinc Anodes: Strategies for Enhanced Performance in Aqueous Zinc-Ion Batteries.先进的锌阳极：水系锌离子电池性能提升策略
Small. 2025 Feb;21(7):e2408138. doi: 10.1002/smll.202408138. Epub 2024 Oct 4.

本文引用的文献

1
Fundamental Understanding of Hydrogen Evolution Reaction on Zinc Anode Surface: A First-Principles Study.锌阳极表面析氢反应的基本理解：第一性原理研究
Nanomicro Lett. 2024 Feb 6;16(1):111. doi: 10.1007/s40820-024-01337-0.
2
An extended substrate screening strategy enabling a low lattice mismatch for highly reversible zinc anodes.一种扩展的底物筛选策略，可实现高度可逆锌阳极的低晶格失配。
Nat Commun. 2024 Jan 25;15(1):753. doi: 10.1038/s41467-024-44893-0.
3
Construct Robust Epitaxial Growth of (101) Textured Zinc Metal Anode for Long Life and High Capacity in Mild Aqueous Zinc-Ion Batteries.
构建用于长寿命和高容量温和水系锌离子电池的具有(101)织构的锌金属阳极的稳健外延生长。
Adv Mater. 2024 Feb;36(5):e2305988. doi: 10.1002/adma.202305988. Epub 2023 Dec 5.
4
Orientational Electrodeposition of Highly (002)-Textured Zinc Metal Anodes Enabled by Iodide Ions for Stable Aqueous Zinc Batteries.碘离子实现的高度（002）织构化锌金属阳极的取向电沉积用于稳定水系锌电池
ACS Nano. 2023 Dec 12;17(23):23861-23871. doi: 10.1021/acsnano.3c08095. Epub 2023 Nov 15.
5
Atomic Pinning of Trace Additives Induces Interfacial Solvation for Highly Reversible Zn Metal Anodes.微量添加剂的原子钉扎作用诱导高度可逆锌金属阳极的界面溶剂化
ACS Nano. 2023 Nov 28;17(22):22722-22732. doi: 10.1021/acsnano.3c07257. Epub 2023 Nov 13.
6
Leveling the Zn Anode by Crystallographic Orientation Manipulation.通过晶体取向操控使锌阳极平整化。
Nano Lett. 2023 Nov 22;23(22):10148-10156. doi: 10.1021/acs.nanolett.3c02379. Epub 2023 Nov 3.
7
Regulating the Interfacial Charge Density by Constructing a Novel Zn Anode-Electrolyte Interface for Highly Reversible Zn Anode.通过构建新型锌负极-电解质界面调控界面电荷密度以实现高度可逆的锌负极
Chemistry. 2024 Jan 11;30(3):e202303211. doi: 10.1002/chem.202303211. Epub 2023 Nov 20.
8
Diagnosing the Electrostatic Shielding Mechanism for Dendrite Suppression in Aqueous Zinc Batteries.诊断水系锌电池中枝晶抑制的静电屏蔽机制
Adv Mater. 2024 Mar;36(9):e2307708. doi: 10.1002/adma.202307708. Epub 2023 Dec 12.
9
Stabilizing Anode-Electrolyte Interface for Dendrite-Free Zn-Ion Batteries Through Orientational Plating with Zinc Aspartate Additive.通过使用天冬氨酸锌添加剂进行取向电镀来稳定无枝晶锌离子电池的阳极-电解质界面
Small. 2024 Mar;20(10):e2306211. doi: 10.1002/smll.202306211. Epub 2023 Oct 24.
10
A biocompatible electrolyte enables highly reversible Zn anode for zinc ion battery.一种生物相容性电解质可实现用于锌离子电池的高度可逆锌阳极。
Nat Commun. 2023 Oct 16;14(1):6526. doi: 10.1038/s41467-023-42333-z.