Biswas Sourav, Negishi Yuichi
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, 162-8601, Tokyo, Japan.
Research Institute for Science & Technology, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, 162-8601, Tokyo, Japan.
Chem Rec. 2024 May;24(5):e202400052. doi: 10.1002/tcr.202400052. Epub 2024 May 22.
The exploration of individual nanoclusters is rapidly advancing, despite stability concerns. To address this challenge, the assembly of cluster nodes through linker molecules has been successfully implemented. However, the linking of the cluster nodes itself introduces a multitude of possibilities, especially when additional factors come into play. While this method proves effective in enhancing material stability, the specific reasons behind its success remain elusive. In our laboratory, we have undertaken extensive studies on Ag cluster-assembled materials. So, here our goal is to establish a model system that allows for the discernment of various factors, eliminating unnecessary complexities during the linking approach. So, we hope that the systematic discourse presented in here will contribute significantly to future endeavors, helping to set clear priorities, and provide solutions to concerns that arise when working with a model system.
尽管存在稳定性方面的担忧，但对单个纳米团簇的探索仍在迅速推进。为应对这一挑战，通过连接分子组装团簇节点已成功实现。然而，团簇节点本身的连接带来了众多可能性，尤其是当其他因素也起作用时。虽然这种方法在提高材料稳定性方面证明是有效的，但其成功背后的具体原因仍不明确。在我们实验室，我们对银团簇组装材料进行了广泛研究。因此，我们的目标是建立一个模型系统，以便能够辨别各种因素，在连接方法中消除不必要的复杂性。所以，我们希望这里呈现的系统性论述将对未来的研究工作做出重大贡献，有助于明确优先事项，并为使用模型系统时出现的问题提供解决方案。
