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利用铁屑固体废物实现生物柴油的优化生产。

Utilization of iron fillings solid waste for optimum biodiesel production.

作者信息

El-Bayoumy Fady I, Osman Ahmed I, Rooney David W, Roushdy Mai H

机构信息

Chemical Engineering Department, Faculty of Engineering, The British University in Egypt (BUE), El-Sherouk City, Egypt.

School of Chemistry and Chemical Engineering, Queen's University Belfast, Belfast, United Kingdom.

出版信息

Front Chem. 2024 May 30;12:1404107. doi: 10.3389/fchem.2024.1404107. eCollection 2024.

DOI:10.3389/fchem.2024.1404107
PMID:38873404
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11169888/
Abstract

This study explores the innovative application of iron filings solid waste, a byproduct from mechanical workshops, as a heterogeneous catalyst in the production of biodiesel from waste cooking oil. Focusing on sustainability and waste valorization, the research presents a dual-benefit approach: addressing the environmental issue of solid waste disposal while contributing to the renewable energy sector. Particle size distribution analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray fluorescence (XRF), Thermal analysis (TG-DTA), and FTIR analysis were used to characterize the iron filings. The response surface methodology (RSM) was used to guide a series of experiments that were conducted to identify the optimum transesterification settings. Important factors that greatly affect the production of biodiesel are identified by the study, including catalyst loading, reaction time, methanol-to-oil ratio, reaction temperature, and stirring rate. The catalyst proved to be successful as evidenced by the 96.4% biodiesel conversion efficiency attained under ideal conditions. The iron filings catalyst's reusability was evaluated, demonstrating its potential for numerous applications without noticeably decreasing activity. This work offers a road towards more environmentally friendly and sustainable chemical processes in energy production by making a strong argument for using industrial solid waste as a catalyst in the biodiesel manufacturing process.

摘要

本研究探索了机械加工车间的副产品铁屑固体废物作为从废食用油生产生物柴油的非均相催化剂的创新应用。该研究聚焦于可持续性和废物增值,提出了一种双重效益的方法:解决固体废物处理的环境问题,同时为可再生能源领域做出贡献。通过粒度分布分析、X射线衍射(XRD)、扫描电子显微镜(SEM)、X射线荧光(XRF)、热分析(TG-DTA)和傅里叶变换红外光谱(FTIR)分析对铁屑进行了表征。响应面法(RSM)用于指导一系列实验,以确定最佳的酯交换反应条件。该研究确定了对生物柴油生产有重大影响的重要因素,包括催化剂负载量、反应时间、甲醇与油的比例、反应温度和搅拌速率。在理想条件下获得的96.4%的生物柴油转化效率证明了该催化剂的成功。对铁屑催化剂进行可重复使用性评估,结果表明其在多次应用中活性无明显下降的潜力。这项工作通过有力论证在生物柴油制造过程中使用工业固体废物作为催化剂,为能源生产中更环保和可持续的化学过程提供了一条途径。

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Sci Rep. 2023 Mar 17;13(1):4430. doi: 10.1038/s41598-023-30961-w.
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The Using of Nanoparticles of Microalgae in Remediation of Toxic Dye from Industrial Wastewater: Kinetic and Isotherm Studies.
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Materials (Basel). 2022 May 31;15(11):3922. doi: 10.3390/ma15113922.
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Widely used catalysts in biodiesel production: a review.生物柴油生产中广泛使用的催化剂:综述
RSC Adv. 2020 Nov 13;10(68):41625-41679. doi: 10.1039/d0ra07931f. eCollection 2020 Nov 11.
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An investigation of biodiesel production from wastes of seafood restaurants.利用海鲜餐馆废弃物生产生物柴油的研究。
Int J Biomater. 2014;2014:609624. doi: 10.1155/2014/609624. Epub 2014 Oct 7.