Savin Raul-Lucian, Ladoși Daniela, Ladoși Ioan, Păpuc Tudor, Becze Anca, Cadar Oana, Torök Iulia, Simedru Dorina, Mariș Ștefania Codruța, Coroian Aurelia
Faculty of Animal Science and Biotechnologies, University of Agricultural Sciences and Veterinary Medicine, 3-5 Mănăștur Street, 400372 Cluj-Napoca, Romania.
INCDO-INOE2000, Research Institute for Analytical Instrumentation, 67 Donath Street, 400293 Cluj-Napoca, Romania.
Foods. 2024 Jun 7;13(12):1790. doi: 10.3390/foods13121790.
Despite the numerous sensory, organoleptic and nutritional qualities, fish meat may also contain some toxic compounds with negative effects on human health. Polycyclic aromatic hydrocarbons (PAHs) are a class of chemicals resulting from incomplete combustion, found at high levels in thermally processed foods, especially in smoked fish. This research studied the influence of wood type (beech, plum and oak) and fish species (rainbow trout, carp and Siberian sturgeon) on PAH contamination in hot smoked fish. Benzo(a)Piren, Σ4PAHs and Σ15PAHs were considered as main indicators of PAH contamination. All-PAHs was quantified in all samples, indicating a specific dynamic of values due to the influence of variables. Generally, BaP (benzo(a)pyrene) content in the samples ranged from 0.11 µg/kg to 8.63 µg/kg, Σ4PAHs from 0.70 µg/kg to 45.24 µg/kg and Σ15PAHs from 17.54 µg/kg to 450.47 µg/kg. Thus, plum wood promoted the highest levels of PAHs, followed by oak and beech. Carp and Siberian sturgeon presented the highest concentrations of PAHs. Some of these parameters had levels that exceeded the limits allowed by legislation via Commission Regulation (EU) No 835/2011. Results revealed BaP levels > 2 µg/kg when plum wood was used in rainbow trout (4.04 µg/kg), carp (4.47 µg/kg) and Siberian sturgeon (8.63 µg/kg). Moreover, the same trend was found for Σ4PAHs, which exceeded 12 µg/kg in rainbow trout (17.57 µg/kg), carp (45.24 µg/kg) and Siberian sturgeon (44.97 µg/kg).
尽管鱼肉具有多种感官、感官特性和营养品质,但鱼肉中也可能含有一些对人体健康有负面影响的有毒化合物。多环芳烃(PAHs)是一类不完全燃烧产生的化学物质,在热加工食品中含量很高,尤其是在烟熏鱼中。本研究考察了木材种类(山毛榉、李子和橡木)和鱼类品种(虹鳟鱼、鲤鱼和西伯利亚鲟鱼)对热熏鱼中多环芳烃污染的影响。苯并(a)芘、Σ4多环芳烃和Σ15多环芳烃被视为多环芳烃污染的主要指标。对所有样品中的总多环芳烃进行了定量分析,结果表明由于变量的影响,其值呈现出特定的动态变化。一般来说,样品中苯并[a]芘(BaP)的含量范围为0.11μg/kg至8.63μg/kg,Σ4多环芳烃的含量范围为0.70μg/kg至45.24μg/kg,Σ15多环芳烃的含量范围为17.54μg/kg至450.47μg/kg。因此,李子木导致的多环芳烃含量最高,其次是橡木和山毛榉。鲤鱼和西伯利亚鲟鱼中的多环芳烃浓度最高。其中一些参数的含量超过了欧盟委员会条例(EU)No 835/2011规定的限量。结果显示,当使用李子木熏制虹鳟鱼(4.04μg/kg)、鲤鱼(4.47μg/kg)和西伯利亚鲟鱼(8.63μg/kg)时,苯并[a]芘含量>2μg/kg。此外,Σ4多环芳烃也呈现出相同的趋势,虹鳟鱼(17.57μg/kg)、鲤鱼(45.24μg/kg)和西伯利亚鲟鱼(44.97μg/kg)中的Σ4多环芳烃含量超过了12μg/kg。