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碳化硅键合石墨烯涂层硅高温加热过程中温度及电导率特性的建模与实验

Modeling and Experiments on Temperature and Electrical Conductivity Characteristics in High-Temperature Heating of Carbide-Bonded Graphene Coating on Silicon.

作者信息

Li Lihua, Wang Ruiying, Huang Yingwei, Li Xingbang

机构信息

Sino-German College of Intelligent Manufacturing, Shenzhen Technology University, Shenzhen 518118, China.

出版信息

Micromachines (Basel). 2024 May 22;15(6):673. doi: 10.3390/mi15060673.

DOI:10.3390/mi15060673
PMID:38930643
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11206079/
Abstract

A novel non-isothermal glass hot embossing system utilizes a silicon mold core coated with a three-dimensional carbide-bonded graphene (CBG) coating, which acts as a thin-film resistance heater. The temperature of the system significantly influences the electrical conductivity properties of silicon with a CBG coating. Through simulations and experiments, it has been established that the electrical conductivity of silicon with a CBG coating gradually increases at lower temperatures and rapidly rises as the temperature further increases. The CBG coating predominantly affects electrical conductivity until 400 °C, after which silicon becomes the dominant factor. Furthermore, the dimensions of CBG-coated silicon and the reduction of CBG coating also affect the rate and outcome of conductivity changes. These findings provide valuable insights for detecting CBG-coated silicon during the embossing process, improving efficiency, and predicting the mold core's service life, thus enhancing the accuracy of optical lens production.

摘要

一种新型非等温玻璃热压花系统采用了涂覆有三维碳化物键合石墨烯(CBG)涂层的硅模具芯,该涂层用作薄膜电阻加热器。系统温度对涂有CBG涂层的硅的电导率特性有显著影响。通过模拟和实验发现,涂有CBG涂层的硅的电导率在较低温度下逐渐增加,随着温度进一步升高则迅速上升。CBG涂层在400°C之前对电导率起主要影响作用,之后硅成为主导因素。此外,涂有CBG涂层的硅的尺寸以及CBG涂层的减少也会影响电导率变化的速率和结果。这些发现为在压花过程中检测涂有CBG涂层的硅、提高效率以及预测模具芯的使用寿命提供了有价值的见解,从而提高了光学镜片生产的精度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/88a1ed68443a/micromachines-15-00673-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/10dc0e860b7b/micromachines-15-00673-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/98d82cbc5ad9/micromachines-15-00673-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/1498c0376df0/micromachines-15-00673-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/30bd97813e91/micromachines-15-00673-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/316f6257ffbf/micromachines-15-00673-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/6c823860d75b/micromachines-15-00673-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/49767fb085c8/micromachines-15-00673-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/88a1ed68443a/micromachines-15-00673-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/10dc0e860b7b/micromachines-15-00673-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/98d82cbc5ad9/micromachines-15-00673-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/1498c0376df0/micromachines-15-00673-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/30bd97813e91/micromachines-15-00673-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/316f6257ffbf/micromachines-15-00673-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/6c823860d75b/micromachines-15-00673-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/49767fb085c8/micromachines-15-00673-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b521/11206079/88a1ed68443a/micromachines-15-00673-g008.jpg

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本文引用的文献

1
Modeling and experimental performance analysis of a novel heating system and its application to glass hot embossing technology.一种新型加热系统的建模与实验性能分析及其在玻璃热压花技术中的应用
Opt Lett. 2019 Jul 15;44(14):3454-3457. doi: 10.1364/OL.44.003454.
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Atomic carbide bonding leading to superior graphene networks.原子碳化键合导致优异的石墨烯网络。
Adv Mater. 2013 Sep 6;25(33):4668-72. doi: 10.1002/adma.201301899. Epub 2013 Jul 15.
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Large-scale pattern growth of graphene films for stretchable transparent electrodes.用于可拉伸透明电极的石墨烯薄膜的大规模图案生长。
Nature. 2009 Feb 5;457(7230):706-10. doi: 10.1038/nature07719. Epub 2009 Jan 14.