Xu Sheng-Zhi, Zhao Tian, Chen Qun, Liang Xin-Gang, Guo Zeng-Yuan
Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Engineering Mechanics, Tsinghua University, Beijing 100084, China.
Fundam Res. 2021 Jul 16;2(1):101-107. doi: 10.1016/j.fmre.2021.07.001. eCollection 2022 Jan.
In thermodynamics, it is essential to distinguish between state functions and process functions. The reason is that the simple compressible thermodynamic system is a bivariate-process system, and the change of internal energy, a state function, corresponds to two process functions, heat and work. Among the state functions in thermodynamics, entropy is a special one because it has to be defined through a process function, exchanged heat , and a unique factor of integration, 1/. In heat transfer, it is shown that Fourier's law and the differential equation of heat conduction are both relations of state quantities alone, and process quantities appear when an integration with respect to time is applied. Moreover, an incompressible heat conduction medium element without conversion between heat and work is a univariate-process system governed by a single variable, temperature. In this case, the change of the thermal energy ("heat content") stored in the system, a state quantity as a function of alone, corresponds to only one process quantity, the transferred heat. Therefore, on the one hand, it is unnecessary to strictly distinguish between state quantities and process quantities in heat transfer, and on the other hand, there is no need to use a factor of integration to prove entransy a state quantity in heat transfer. Thermodynamics and heat transfer are two parallel sub-disciplines in thermal science. It is incorrect to deny entransy as a state quantity in heat transfer by the uniqueness of the factor of integration for entropy in thermodynamics, and entransy has significant physical meaning in the analysis and optimization of heat transfer processes.
在热力学中,区分状态函数和过程函数至关重要。原因在于简单可压缩热力学系统是二元过程系统,而作为状态函数的内能变化对应于两个过程函数,即热量和功。在热力学的状态函数中,熵是特殊的一个,因为它必须通过一个过程函数(交换热量 )和一个唯一的积分因子(1/ )来定义。在热传递中,傅里叶定律和热传导微分方程都仅是状态量之间的关系,只有在对时间进行积分时过程量才会出现。此外,一个不发生热与功转换的不可压缩热传导介质元是由单一变量温度控制的一元过程系统。在这种情况下,系统中储存的热能(“热含量”)作为仅关于 的函数的状态量的变化仅对应于一个过程量,即传递的热量。因此,一方面,在热传递中没有必要严格区分状态量和过程量,另一方面,也无需用积分因子来证明能质传递是热传递中的一个状态量。热力学和热传递是热科学中两个平行的子学科。以热力学中熵的积分因子的唯一性来否定能质传递作为热传递中的状态量是不正确的,并且能质传递在热传递过程的分析和优化中具有重要的物理意义。