α-酮酸和草氨酸的光化学自由基脱羧二硫化反应
Photochemical radical decarboxylative disulfuration of α-keto acids and oxamic acids.
作者信息
Sun Huangbin, Bin Xueting, Zhang Qianfang, Chen Xiaowen, Tang Jie, Jiang Guofang
机构信息
College of Chemistry and Chemical Engineering, State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, Hunan University, Changsha 410082, P. R. China.
School of Materials and Environmental Engineering, Shenzhen Polytechnic University, Shenzhen 518055, P. R. China.
出版信息
Chem Commun (Camb). 2024 Jul 30;60(62):8107-8110. doi: 10.1039/d4cc01914h.
A visible-light-induced directed decarboxylative disulfuration of α-keto acids and oxamic acids was developed. As a result, a series of versatile mono acyl disulfide derivatives was synthesized under mild and sustainable reaction conditions. This protocol has a broad substrate scope, good functional-group tolerance, and excellent synthetic applications.
我们开发了一种可见光诱导的α-酮酸和草氨酸的定向脱羧二硫化反应。结果，在温和且可持续的反应条件下合成了一系列通用的单酰基二硫醚衍生物。该方法具有广泛的底物范围、良好的官能团耐受性和出色的合成应用。
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