Ghediya Prashant R, Magari Yusaku, Sadahira Hikaru, Endo Takashi, Furuta Mamoru, Zhang Yuqiao, Matsuo Yasutaka, Ohta Hiromichi
Research Institute for Electronic Science, Hokkaido University, N20W10, Kita, Sapporo, 001-0020, Japan.
Graduate School of Information Science and Technology, Hokkaido University, N14W9, Kita, Sapporo, 060-0814, Japan.
Small Methods. 2025 Jan;9(1):e2400578. doi: 10.1002/smtd.202400578. Epub 2024 Aug 3.
Transparent oxide semiconductors (TOSs) based thin-film transistors (TFTs) that exhibit higher field effect mobility (µ) are highly required toward the realization of next-generation displays. Among numerous types of TOS-TFTs, InO-based TFTs are the front-running candidate because they exhibit the highest µ ≈100 cm V s. However, the device operation of InO TFTs is unreliable; a large voltage shift occurs especially when negative gate bias is applied due to adsorption/desorption of gas molecules. Although passivation of the TFTs is used to overcome such instability, previously proposed passivation materials do not improve the reliability. Here, it is shown that the InO TFTs passivated with YO and ErO films are highly reliable and do not show threshold voltage shifts when applying gate bias. Positive and negative gate bias is applied to the InO TFTs passivated with various insulating oxides and found that only the InO TFTs passivated with YO and ErO films do not exhibit threshold voltage shifts. It is observed that only the YO grew heteroepitaxially on the InO crystal. This is the origin of the high reliability of the InO TFTs passivated with YO and ErO films. This finding accelerates the development of next-generation displays using high-mobility InO TFTs.
为实现下一代显示器,对基于透明氧化物半导体(TOS)的薄膜晶体管(TFT)有着强烈需求,这类晶体管需展现出更高的场效应迁移率(µ)。在众多类型的TOS-TFT中,基于InO的TFT是领先的候选者,因为它们展现出最高的µ≈100 cm² V⁻¹ s⁻¹。然而,InO TFT的器件操作不可靠;特别是在施加负栅极偏压时,由于气体分子的吸附/解吸会发生大的电压偏移。尽管使用TFT的钝化来克服这种不稳定性,但先前提出的钝化材料并未提高可靠性。在此表明,用YO和ErO薄膜钝化的InO TFT具有高度可靠性,在施加栅极偏压时不会出现阈值电压偏移。对用各种绝缘氧化物钝化的InO TFT施加正、负栅极偏压,发现只有用YO和ErO薄膜钝化的InO TFT没有出现阈值电压偏移。观察到只有YO在InO晶体上异质外延生长。这就是用YO和ErO薄膜钝化的InO TFT具有高可靠性的原因。这一发现加速了使用高迁移率InO TFT的下一代显示器的开发。