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电磁悬浮下Ti-48Al废料精炼过程中氧元素迁移规律的研究

Study on the Migration Patterns of Oxygen Elements during the Refining Process of Ti-48Al Scrap under Electromagnetic Levitation.

作者信息

Pang Xinchen, Zhang Guifang, Yan Peng, Xiao Zhixiang, Wang Xiaoliang

机构信息

Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China.

出版信息

Materials (Basel). 2024 Jul 26;17(15):3709. doi: 10.3390/ma17153709.

DOI:10.3390/ma17153709
PMID:39124373
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11313487/
Abstract

This study investigated the migration patterns of oxygen in the deoxidation process of Ti-48Al alloy scrap using electromagnetic levitation (EML) technology. Scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) were employed to analyze the oxygen distribution patterns and migration path during EML. The refining process resulted in three types of oxygen migration: (1) escape from the lattice and evaporation in the form of AlO, AlO; (2) formation of metal oxides and remaining in the alloy melt; (3) attachment to the quartz tube wall in the form of metal oxides such as AlO and CrO. The oxygen content of the scrap was dropped with a deoxidation ratio of 62%. It indicated that EML can greatly promote the migration and removal of oxygen elements in Ti-Al alloy scrap.

摘要

本研究利用电磁悬浮(EML)技术研究了Ti-48Al合金废料脱氧过程中氧的迁移模式。采用扫描电子显微镜(SEM)、X射线衍射(XRD)和X射线光电子能谱(XPS)分析了电磁悬浮过程中氧的分布模式和迁移路径。精炼过程导致了三种类型的氧迁移:(1)从晶格中逸出并以AlO、AlO的形式蒸发;(2)形成金属氧化物并残留在合金熔体中;(3)以AlO和CrO等金属氧化物的形式附着在石英管壁上。废料的氧含量下降,脱氧率为62%。这表明电磁悬浮可以极大地促进Ti-Al合金废料中氧元素的迁移和去除。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/0f814da04f1c/materials-17-03709-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/850574e06dad/materials-17-03709-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/e977fc3066ed/materials-17-03709-g003.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/26d2d6ba6a0f/materials-17-03709-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/02d1e0c96ea1/materials-17-03709-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/0f814da04f1c/materials-17-03709-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/850574e06dad/materials-17-03709-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/f0ed1ce91c82/materials-17-03709-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/e977fc3066ed/materials-17-03709-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/afb85d5c4384/materials-17-03709-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/f0580e52dc35/materials-17-03709-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/26d2d6ba6a0f/materials-17-03709-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/02d1e0c96ea1/materials-17-03709-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4a1/11313487/0f814da04f1c/materials-17-03709-g008.jpg

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