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用于选择性检测铁及降解水样中Fe/碱性红9络合物的氮掺杂碳点

N-Doped Carbon Dots for Selective Detection of Fe and Degradation of Fe/Basic Red 9 Complexes in Water Samples.

作者信息

Wang Caixia, Qiao Chengkui, Tian Fajun, Guo Linlin, Wang Ruiping, Li Jun, Pang Tao, Pang Rongli, Xie Hanzhong

机构信息

Zhengzhou Fruit Research Institute, Chinese Academy of Agricultural Sciences, Zhengzhou, 450009, China.

出版信息

J Fluoresc. 2024 Aug 17. doi: 10.1007/s10895-024-03894-4.

Abstract

In this work, the eco-friendly N-doped carbon dots KF-CDs and A-CDs were derived from kiwifruit by a simple one-step hydrothermal strategy at 180 °C for 6 h. KF-CDs have a high fluorescence quantum yield (27.85%), it is obviously rapid quenched by Fe, and have a good linear relationship from 1 to 8.26 µM (the detection limit was 0.077 µM). Basic red 9 is extensively used in biological, environmental and industry. Although it makes a great contribution to the economy, its toxicity should be taken seriously, especially with harmful metal ions. Within 2 h, A-CDs could degrade basic red 9 with degradation efficiency 89.6%, even though there was a stable compound formed with Fe that the degradation efficiency was up to 88.3%. The results complement the research blank of carbon dots in catalytic degradation of basic red 9.

摘要

在本工作中,通过在180℃下简单的一步水热法,以猕猴桃为原料制备了环境友好型的氮掺杂碳点KF-CDs和A-CDs,反应时间为6小时。KF-CDs具有较高的荧光量子产率(27.85%),能被铁显著快速猝灭,在1至8.26μM范围内具有良好的线性关系(检测限为0.077μM)。碱性红9广泛应用于生物、环境和工业领域。尽管它对经济有很大贡献,但其毒性应受到重视,尤其是与有害金属离子相关时。在2小时内,A-CDs能够降解碱性红9,降解效率为89.6%,即使与铁形成稳定化合物时,降解效率仍高达88.3%。这些结果填补了碳点在催化降解碱性红9方面的研究空白。

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