Wang Caixia, Qiao Chengkui, Tian Fajun, Guo Linlin, Wang Ruiping, Li Jun, Pang Tao, Pang Rongli, Xie Hanzhong
Zhengzhou Fruit Research Institute, Chinese Academy of Agricultural Sciences, Zhengzhou, 450009, China.
J Fluoresc. 2024 Aug 17. doi: 10.1007/s10895-024-03894-4.
In this work, the eco-friendly N-doped carbon dots KF-CDs and A-CDs were derived from kiwifruit by a simple one-step hydrothermal strategy at 180 °C for 6 h. KF-CDs have a high fluorescence quantum yield (27.85%), it is obviously rapid quenched by Fe, and have a good linear relationship from 1 to 8.26 µM (the detection limit was 0.077 µM). Basic red 9 is extensively used in biological, environmental and industry. Although it makes a great contribution to the economy, its toxicity should be taken seriously, especially with harmful metal ions. Within 2 h, A-CDs could degrade basic red 9 with degradation efficiency 89.6%, even though there was a stable compound formed with Fe that the degradation efficiency was up to 88.3%. The results complement the research blank of carbon dots in catalytic degradation of basic red 9.
在本工作中,通过在180℃下简单的一步水热法,以猕猴桃为原料制备了环境友好型的氮掺杂碳点KF-CDs和A-CDs,反应时间为6小时。KF-CDs具有较高的荧光量子产率(27.85%),能被铁显著快速猝灭,在1至8.26μM范围内具有良好的线性关系(检测限为0.077μM)。碱性红9广泛应用于生物、环境和工业领域。尽管它对经济有很大贡献,但其毒性应受到重视,尤其是与有害金属离子相关时。在2小时内,A-CDs能够降解碱性红9,降解效率为89.6%,即使与铁形成稳定化合物时,降解效率仍高达88.3%。这些结果填补了碳点在催化降解碱性红9方面的研究空白。