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评估 GO/ZnO 纳米复合材料在太阳能辅助光催化降解工业染料和纺织废水中的应用。

Assessment of GO/ZnO nanocomposite for solar-assisted photocatalytic degradation of industrial dye and textile effluent.

机构信息

Amity Institute of Nanotechnology, Amity University, Sector 125, Noida, 201313, India.

Department of Physics, Indian Institute of Technology Kharagpur, Kharagpur, 721302, India.

出版信息

Environ Sci Pollut Res Int. 2020 Sep;27(25):32076-32087. doi: 10.1007/s11356-020-08849-3. Epub 2020 Jun 6.

Abstract

An ecofriendly and solar light-responsive graphene oxide wrapped zinc oxide nanohybrid has been synthesized hydrothermally using lemon and honey respectively as chelating and complexing agents. By tuning the reaction conditions, a heterostructure between GO and ZnO has been formed during synthesis. The photocatalytic activity of the synthesized nanohybrid was investigated by degradation of hazardous organic textile dye (methylene blue) as well as wastewater under natural solar light. The nanohybrid exhibited excellent photocatalytic activity towards degradation (~ 89%) of methylene blue (MeB). Furthermore, along with decolorization, 71% of mineralization was also achieved. Interestingly, the nanohybrid has been found to be reusable up to 4 cycles without significant loss of photocatalytic activity. Along with this, the physicochemical parameters of the wastewater generated from textile industry have been also monitored before and after exposure to nanohybrid. The results revealed significant reduction in chemical oxygen demand (COD) (96.33%), biochemical oxygen demand (BOD) (96.23%), and total dissolved solids (TDS) (20.85%), suggesting its potential applicability in textile wastewater treatment.

摘要

一种环保且对阳光响应的石墨烯氧化物包裹的氧化锌纳米杂化材料,通过水热法分别使用柠檬和蜂蜜作为螯合剂和络合剂合成。通过调节反应条件,在合成过程中形成了 GO 和 ZnO 之间的异质结构。通过降解危险的有机纺织染料(亚甲基蓝)以及在自然光下处理废水,研究了合成纳米杂化材料的光催化活性。纳米杂化材料对亚甲基蓝(MeB)的降解表现出优异的光催化活性(~89%)。此外,伴随着脱色,还实现了 71%的矿化。有趣的是,纳米杂化材料在经过 4 次重复使用后,仍然保持了较高的光催化活性,没有明显的损失。此外,还监测了纺织工业废水在暴露于纳米杂化材料前后的物理化学参数。结果表明,化学需氧量(COD)(96.33%)、生化需氧量(BOD)(96.23%)和总溶解固体(TDS)(20.85%)显著降低,表明其在纺织废水处理方面具有潜在的应用前景。

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