Wei Shuxian, He Chuan, Zhang Lanyue, Li Canhua, Li Jiamao, DU Gang
School of Metallurgical Engineering, Anhui University of Technology Maanshan Anhui 243002 China
Jiuquan Vocationl and Technical College Jiuquan GanSu 735000 China.
RSC Adv. 2024 Aug 20;14(36):26272-26291. doi: 10.1039/d4ra04336g. eCollection 2024 Aug 16.
The pollutants such as heavy metals, organic matter, and nitrates in soil and water pose challenges to environmental remediation technology. Nano zero valent iron has shown enormous potential in the field of environmental remediation due to its excellent adsorption performance. By using carbon based materials, rock minerals, biomolecules, , as supporting materials for nZVI, and through structural and performance modifications, its performance has been successfully optimized, reducing defects such as aggregation and easy oxidation of the material. This article compares and summarizes the modification effects of different loadings on nZVI, and comprehensively reviews the latest progress, preparation methods, and application of nZVI particles in soil and water remediation. Specifically, this article explores in detail the impact and mechanism of nZVI particles in commonly used antibiotics contaminated environments. Firstly, the combination methods of different types of materials with zero valent iron, as well as the synthesis methods and application scenarios of nZVI, were integrated. Secondly, the interaction mechanism between pollutants and nZVI was introduced in detail, including adsorption, redox reactions, and co-precipitation. Subsequently, environmental factors that affect repair efficiency were emphasized, such as pH value, coexisting components, oxygen, contact time, and temperature. Finally, the challenges faced by the application of nZVI in actual polluted soil and water bodies, as well as the prospects for its long-term efficacy and safety evaluation, are proposed to promote further development in the future.
土壤和水中的重金属、有机物和硝酸盐等污染物对环境修复技术构成挑战。纳米零价铁因其优异的吸附性能在环境修复领域展现出巨大潜力。通过使用碳基材料、岩石矿物、生物分子等作为纳米零价铁的载体材料,并通过结构和性能改性,成功优化了其性能,减少了材料团聚和易氧化等缺陷。本文比较并总结了不同负载对纳米零价铁的改性效果,全面综述了纳米零价铁颗粒在土壤和水修复中的最新进展、制备方法及应用。具体而言,本文详细探讨了纳米零价铁颗粒在常用抗生素污染环境中的影响及作用机制。首先,整合了不同类型材料与零价铁的复合方法以及纳米零价铁的合成方法和应用场景。其次,详细介绍了污染物与纳米零价铁之间的相互作用机制,包括吸附、氧化还原反应和共沉淀。随后,强调了影响修复效率的环境因素,如pH值、共存成分、氧气、接触时间和温度。最后,提出了纳米零价铁在实际污染土壤和水体应用中面临的挑战以及其长期效果和安全性评价的前景,以促进未来的进一步发展。