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利用纳米零价铁去除废水中常见抗生素的研究进展。

Advancements in removing common antibiotics from wastewater using nano zero valent iron.

作者信息

Wei Shuxian, He Chuan, Zhang Lanyue, Li Canhua, Li Jiamao, DU Gang

机构信息

School of Metallurgical Engineering, Anhui University of Technology Maanshan Anhui 243002 China

Jiuquan Vocationl and Technical College Jiuquan GanSu 735000 China.

出版信息

RSC Adv. 2024 Aug 20;14(36):26272-26291. doi: 10.1039/d4ra04336g. eCollection 2024 Aug 16.

DOI:10.1039/d4ra04336g
PMID:39165794
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11333996/
Abstract

The pollutants such as heavy metals, organic matter, and nitrates in soil and water pose challenges to environmental remediation technology. Nano zero valent iron has shown enormous potential in the field of environmental remediation due to its excellent adsorption performance. By using carbon based materials, rock minerals, biomolecules, , as supporting materials for nZVI, and through structural and performance modifications, its performance has been successfully optimized, reducing defects such as aggregation and easy oxidation of the material. This article compares and summarizes the modification effects of different loadings on nZVI, and comprehensively reviews the latest progress, preparation methods, and application of nZVI particles in soil and water remediation. Specifically, this article explores in detail the impact and mechanism of nZVI particles in commonly used antibiotics contaminated environments. Firstly, the combination methods of different types of materials with zero valent iron, as well as the synthesis methods and application scenarios of nZVI, were integrated. Secondly, the interaction mechanism between pollutants and nZVI was introduced in detail, including adsorption, redox reactions, and co-precipitation. Subsequently, environmental factors that affect repair efficiency were emphasized, such as pH value, coexisting components, oxygen, contact time, and temperature. Finally, the challenges faced by the application of nZVI in actual polluted soil and water bodies, as well as the prospects for its long-term efficacy and safety evaluation, are proposed to promote further development in the future.

摘要

土壤和水中的重金属、有机物和硝酸盐等污染物对环境修复技术构成挑战。纳米零价铁因其优异的吸附性能在环境修复领域展现出巨大潜力。通过使用碳基材料、岩石矿物、生物分子等作为纳米零价铁的载体材料,并通过结构和性能改性,成功优化了其性能,减少了材料团聚和易氧化等缺陷。本文比较并总结了不同负载对纳米零价铁的改性效果,全面综述了纳米零价铁颗粒在土壤和水修复中的最新进展、制备方法及应用。具体而言,本文详细探讨了纳米零价铁颗粒在常用抗生素污染环境中的影响及作用机制。首先,整合了不同类型材料与零价铁的复合方法以及纳米零价铁的合成方法和应用场景。其次,详细介绍了污染物与纳米零价铁之间的相互作用机制,包括吸附、氧化还原反应和共沉淀。随后,强调了影响修复效率的环境因素,如pH值、共存成分、氧气、接触时间和温度。最后,提出了纳米零价铁在实际污染土壤和水体应用中面临的挑战以及其长期效果和安全性评价的前景,以促进未来的进一步发展。

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本文引用的文献

1
Accumulation of antibiotics in the environment: Have appropriate measures been taken to protect Canadian human and ecological health?抗生素在环境中的积累:是否采取了适当措施来保护加拿大的人类和生态健康?
Ecotoxicol Environ Saf. 2024 Jul 15;280:116513. doi: 10.1016/j.ecoenv.2024.116513. Epub 2024 May 30.
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Infect Med (Beijing). 2024 Feb 19;3(1):100092. doi: 10.1016/j.imj.2024.100092. eCollection 2024 Mar.
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Exploring zeolite-based composites in adsorption and photocatalysis for toxic wastewater treatment: Preparation, mechanisms, and future perspectives.
沸石基复合材料在吸附和光催化处理有毒废水中的应用:制备、机理及未来展望。
Environ Pollut. 2024 May 15;349:123922. doi: 10.1016/j.envpol.2024.123922. Epub 2024 Apr 3.
4
A review on the alternatives to antibiotics and the treatment of antibiotic pollution: Current development and future prospects.抗生素替代品与抗生素污染治理的研究进展:现状与未来展望。
Sci Total Environ. 2024 May 20;926:171757. doi: 10.1016/j.scitotenv.2024.171757. Epub 2024 Mar 19.
5
Deciphering the removal of antibiotics and the antibiotic resistome from typical hospital wastewater treatment systems.解析典型医院污水处理系统中抗生素及抗生素抗性组的去除。
Sci Total Environ. 2024 May 20;926:171806. doi: 10.1016/j.scitotenv.2024.171806. Epub 2024 Mar 19.
6
Synergistic effect and mechanism of nZVI/LDH composites adsorption coupled reduction of nitrate in micro-polluted water.纳米零价铁/层状双氢氧化物复合材料对微污染水中硝酸盐吸附耦合还原的协同效应及机制
J Hazard Mater. 2024 Feb 15;464:133023. doi: 10.1016/j.jhazmat.2023.133023. Epub 2023 Nov 17.
7
A review on nitrates' health benefits and disease prevention.硝酸盐的健康益处与疾病预防综述。
Nitric Oxide. 2024 Jan 1;142:1-15. doi: 10.1016/j.niox.2023.11.003. Epub 2023 Nov 20.
8
Effects of water environmental factors and antibiotics on bacterial community in urban landscape lakes.水环境因子和抗生素对城市景观湖泊细菌群落的影响
Aquat Toxicol. 2023 Dec;265:106740. doi: 10.1016/j.aquatox.2023.106740. Epub 2023 Nov 4.
9
Unveiling global public interest and seasonal patterns of antibiotics and antibiotic resistance: An infodemiology study with implications for public health awareness and intervention strategies.揭示全球公众利益和抗生素及抗生素耐药性的季节性模式:一项具有公共卫生意识和干预策略意义的信息流行病学研究。
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10
Calcium alginate-nZVI-biochar for removal of Pb/Zn/Cd in water: Insights into governing mechanisms and performance.用于去除水中铅/锌/镉的海藻酸钙-nZVI-生物炭:对控制机制和性能的见解
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