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从蔓花生和马齿苋中合成的发光 TiO2 纳米粒子用于染料降解、抗菌和抗氧化性能。

Luminescent TiO nanoparticles synthesized from Mollugo Oppositifolia and Trianthema Portulacastrum for dye degradation, antimicrobial and antioxidant properties.

机构信息

SSM College of Arts and Science, Dindigul, Tamil Nadu, India.

Department of Chemistry, DharmapuramAdhinam Arts College, Mayiladuthurai, Tamil Nadu, India.

出版信息

Luminescence. 2024 Aug;39(8):e4847. doi: 10.1002/bio.4847.

Abstract

In modern times, nanoparticles have materialized as indispensable things in contemporary medicine, with a variety of uses in clinical, drug and gene conveyance. In the present study, TiO nanoparticles (NPs) prepared from the leaf extracts of Mollugooppositifolia and Trianthema portulacastrum were compared with the chemical TiO-NPs for antibacterial and antioxidant activities and environment-friendly nature through various tools like the UV-visible, X-ray diffraction with the aid of other analytical techniques like HR-TEM, Fourier transform infrared (FT-IR) and photoluminescence spectroscopic techniques. The morphology of green TiO-NPs is found to be spherical, which is supported by HR-TEM images. FT-IR analyses and X-ray diffraction data ensure that the polycrystalline characters of TiO-NPs alike to the presence of metal oxide. TiO-NPs showed a possible photocatalytic activity for the ruin of acid black 1 dye after disclosure to sunlight. The chemical and green methods of TiO-NPs have acid black 1 dye decomposition rates of 86.66% and 94.33%, respectively. The synthesized TiO-NPs are also assessed for antimicrobial and antioxidant activities. Green TiO-NPs exhibit antibacterial activity against Pseudomonas aeruginosa (17 + 0.56 mm) and Staphylococcus aureus (16 + 0.24 mm) at concentrations as low as 100 μL. The green TiO-NPs showed high inhibition of DPPH I radical (50 μg/m) at 95.17 ± 21. Therefore, TiO-NPs represent eco-friendly properties that aid in the degradation of dyes due to their antioxidant activity.

摘要

在现代,纳米颗粒已成为当代医学中不可或缺的物质,在临床、药物和基因传递等方面有多种用途。在本研究中,通过各种工具,如紫外-可见分光光度计、X 射线衍射,并辅以高分辨率透射电子显微镜(HR-TEM)、傅里叶变换红外(FT-IR)和光致发光光谱技术等分析技术,比较了从紫堇和蕺菜叶提取物中制备的 TiO 纳米颗粒(NPs)与化学 TiO-NPs 的抗菌和抗氧化活性以及环境友好性。绿 TiO-NPs 的形态被发现为球形,这得到了 HR-TEM 图像的支持。FT-IR 分析和 X 射线衍射数据确保了 TiO-NPs 的多晶特性类似于金属氧化物的存在。TiO-NPs 在暴露于阳光后显示出对酸性黑 1 染料的光催化活性。化学法和绿色法制备的 TiO-NPs 对酸性黑 1 染料的分解率分别为 86.66%和 94.33%。还评估了合成的 TiO-NPs 的抗菌和抗氧化活性。绿 TiO-NPs 对铜绿假单胞菌(17 + 0.56 mm)和金黄色葡萄球菌(16 + 0.24 mm)具有抗菌活性,浓度低至 100 μL。绿 TiO-NPs 对 DPPH I 自由基(50 μg/m)的抑制率高达 95.17 ± 21. 因此,TiO-NPs 具有环保特性,由于其抗氧化活性,有助于染料的降解。

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