使用金属有机框架（MOF）材料进行二氧化碳捕获与转化：综述

Carbon Dioxide Capture and Conversion Using Metal-Organic Framework (MOF) Materials: A Comprehensive Review.

作者信息

Kong Fanyi, Chen Wenqian

机构信息

Key Laboratory of Organic Compound Pollution Control Engineering (MOE), School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China.

出版信息

Nanomaterials (Basel). 2024 Aug 12;14(16):1340. doi: 10.3390/nano14161340.

DOI:10.3390/nano14161340

PMID:39195378

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11356948/

Abstract

The escalating threat of anthropogenic climate change has spurred an urgent quest for innovative CO capture and utilization (CCU) technologies. Metal-organic frameworks (MOFs) have emerged as prominent candidates in CO capture and conversion due to their large specific surface area, well-defined porous structure, and tunable chemical properties. This review unveils the latest advancements in MOF-based materials specifically designed for superior CO adsorption, precise separation, advanced photocatalytic and electrocatalytic CO reduction, progressive CO hydrogenation, and dual functionalities. We explore the strategies that enhance MOF efficiency and examine the challenges of and opportunities afforded by transitioning from laboratory research to industrial application. Looking ahead, this review offers a visionary perspective on harnessing MOFs for the sustainable capture and conversion of CO.

摘要

人为气候变化带来的威胁不断升级，促使人们迫切寻求创新的二氧化碳捕获与利用（CCU）技术。金属有机框架材料（MOF）因其具有大比表面积、明确的多孔结构和可调节的化学性质，已成为二氧化碳捕获与转化领域的重要候选材料。本综述揭示了基于MOF的材料在高效二氧化碳吸附、精确分离、先进的光催化和电催化二氧化碳还原、渐进式二氧化碳加氢以及双重功能方面的最新进展。我们探讨了提高MOF效率的策略，并审视了从实验室研究向工业应用转变所面临的挑战和机遇。展望未来，本综述为利用MOF实现二氧化碳的可持续捕获与转化提供了前瞻性视角。