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香烟烟雾作用下颌面硅橡胶弹性体的颜色变化

Color Modifications of a Maxillofacial Silicone Elastomer under the Effect of Cigarette Smoke.

作者信息

Gradinariu Anca Irina, Stoica Alexandru-Constantin, Bargan Alexandra, Racles Carmen, Stelea Carmen Gabriela, Costan Victor Vlad

机构信息

Department of Oral and Maxillofacial Surgery, "Grigore T. Popa" University of Medicine and Pharmacy, 16 University Street, 700511 Iasi, Romania.

Department of Inorganic Polymers, "Petru Poni" Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, 700487 Iasi, Romania.

出版信息

Materials (Basel). 2024 Aug 17;17(16):4089. doi: 10.3390/ma17164089.

Abstract

Although it is known (from the observations of medical professionals) that cigarette smoke negatively affects maxillofacial prostheses, especially through staining/discoloration, systematic research in this regard is limited. Herein, the color modifications of M511 maxillofacial silicone, unpigmented and pigmented with red or skin tone pigments, covered with mattifiers, or with makeup and mattifiers, and directly exposed to cigarette smoke, were investigated by spectrophotometric measurements in the CIELab and RGB color systems. The changes in color parameters are comparatively discussed, showing that the base silicone material without pigmentation and coating undergoes the most significant modifications. Visible and clinically unacceptable changes occurred after direct exposure to only 20 cigarettes. By coating and application of makeup, the material is more resistant to color changes, which suggests that surface treatments provide increased protection to adsorption of the smoke components. The dynamic water vapor sorption (DVS) measurements indicate a decrease of the sorption capacity in pigmented versus unpigmented elastomers, in line with the changes in color parameters.

摘要

尽管(从医学专业人员的观察中)已知香烟烟雾会对颌面修复体产生负面影响,尤其是通过染色/变色,但这方面的系统性研究有限。在此,通过在CIELab和RGB颜色系统中进行分光光度测量,研究了M511颌面硅橡胶的颜色变化,该硅橡胶未着色、用红色或肤色颜料着色、覆盖有哑光剂、或使用了化妆品和哑光剂,并直接暴露于香烟烟雾中。对颜色参数的变化进行了比较讨论,结果表明未着色且未涂层的基础硅橡胶材料发生的变化最为显著。仅直接暴露于20支香烟后,就出现了明显且临床上不可接受的变化。通过涂层和使用化妆品,材料对颜色变化的抵抗力更强,这表明表面处理能增强对烟雾成分吸附的保护作用。动态水蒸气吸附(DVS)测量表明,与未着色的弹性体相比,着色弹性体的吸附能力有所下降,这与颜色参数的变化一致。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d792/11356476/bf94ec22e1fd/materials-17-04089-sch001.jpg

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