利用海枣提取物绿色合成氧化镁纳米颗粒及其光催化活性

Green synthesis of magnesium oxide nanoparticles using Hyphaene thebaica extract and their photocatalytic activities.

作者信息

Muhaymin Abdul, Mohamed Hamza Elsayed Ahmed, Hkiri Khaoula, Safdar Ammara, Azizi Shohreh, Maaza Malik

机构信息

College of Graduate Studies, UNESCO-UNISA Africa Chair in Nanosciences-Nanotechnology, University of South Africa, Muckleneuk Ridge, P.O. Box 392, Pretoria, South Africa.

Material Research Department (MRD), Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, 1 Old Faure Road, Somerset West, PO Box 722, Somerset West, 7129, Western Cape, South Africa.

出版信息

Sci Rep. 2024 Aug 29;14(1):20135. doi: 10.1038/s41598-024-71149-0.

Abstract

Magnesium oxide nanoparticles (MgO NPs) represent an interesting inorganic material widely utilized across various fields including sensing, antimicrobial applications, optical coatings, water purification, fuel additives, absorbents, and catalysis, owing to their exceptional broad energy band gap, surface affinity, and strong chemical and thermal durability. In this investigation, MgO NPs were successfully synthesized through a green approach employing fruit extract from the gingerbread tree (Hyphaene thebaica). Analysis via scanning electron microscopy (SEM) and transmission electron microscopy (TEM) confirmed their agglomerated quasi-spherical shape with a size range of 20-60 nm. The X-ray diffraction (XRD) pattern exhibited prominent peaks at planes (200) and (220), indicating the high crystallinity of MgO NPs with a crystallite size of 32.6 ± 5 nm while Energy-dispersive X-ray spectroscopy (EDS) analysis highlighted the composition comprises 40.47% Magnesium and 48.64% Oxygen by weight. Fourier transform infrared spectroscopy (FT-IR) revealed characteristic Mg-O bonds through peaks at 560 cm and 866 cm, while Raman spectroscopy affirmed the cubic structure of MgO. Subsequently, the photocatalytic performance of MgO NPs under visible light irradiation was evaluated. Remarkably, the addition of 1 g/L of MgO nano-catalyst resulted in a degradation efficiency of 98% after 110 min on methylene blue dye, showcasing the high catalytic activity of MgO NPs. This remarkable photocatalytic efficiency emphasizes the potential of MgO NPs in environmental remediation.

摘要

氧化镁纳米颗粒(MgO NPs)是一种有趣的无机材料,由于其具有出色的宽带隙、表面亲和力以及强大的化学和热稳定性,被广泛应用于传感、抗菌应用、光学涂层、水净化、燃料添加剂、吸收剂和催化等各个领域。在本研究中,通过采用姜饼树(Hyphaene thebaica)果实提取物的绿色方法成功合成了MgO NPs。通过扫描电子显微镜(SEM)和透射电子显微镜(TEM)分析证实了它们呈团聚的准球形,尺寸范围为20 - 60纳米。X射线衍射(XRD)图谱在(200)和(220)晶面处显示出明显的峰,表明MgO NPs具有高结晶度,微晶尺寸为32.6 ± 5纳米,而能量色散X射线光谱(EDS)分析突出显示其组成按重量计包含40.47%的镁和48.64%的氧。傅里叶变换红外光谱(FT - IR)通过560厘米和866厘米处的峰揭示了特征性的Mg - O键,而拉曼光谱证实了MgO的立方结构。随后,评估了MgO NPs在可见光照射下的光催化性能。值得注意的是,添加1克/升的MgO纳米催化剂在110分钟后对亚甲基蓝染料的降解效率达到了98%,展示了MgO NPs的高催化活性。这种显著的光催化效率强调了MgO NPs在环境修复方面的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9015/11362519/34b1bf237797/41598_2024_71149_Fig1_HTML.jpg

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