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光热转换在有机合成中的最新应用

Recent Applications of Photothermal Conversion in Organic Synthesis.

作者信息

Matter Megan E, Tagnon Clotilde, Stache Erin E

机构信息

Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States.

出版信息

ACS Cent Sci. 2024 Aug 5;10(8):1460-1472. doi: 10.1021/acscentsci.4c00545. eCollection 2024 Aug 28.

Abstract

Photothermal conversion is a novel heating method that has emerged in recent years, wherein certain species can convert light to heat with great efficiency. These photothermal agents have shown immense promise for generating nanoscale thermal gradients under mild, visible light irradiation, providing a pathway for combining photochemistry with thermally driven reactivity. While this novel heating mechanism has been leveraged to great effect for applications such as photothermal therapeutics and steam water purification, it has seen limited use in organic synthesis. This outlook explores instances wherein the photothermal effect was used directly or as a synergistic component to drive organic reactions and postulates how it may be used moving forward.

摘要

光热转换是近年来出现的一种新型加热方法,某些物质能够高效地将光转化为热。这些光热剂在温和的可见光照射下产生纳米级热梯度方面展现出了巨大的潜力,为光化学与热驱动反应性的结合提供了一条途径。虽然这种新型加热机制已在光热疗法和蒸汽水净化等应用中发挥了巨大作用,但在有机合成中的应用却十分有限。本展望探讨了光热效应直接或作为协同组分用于驱动有机反应的实例,并推测了其未来的应用方式。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5b9f/11363323/ca859bc2f52b/oc4c00545_0001.jpg

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