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苯甲酰氯处理对枣椰树/聚氯乙烯(PVC)复合材料的形态、热、机械和水热老化性能的影响。

Effect of benzoyl chloride treatment on morphological, thermal, mechanical, and hydrothermal aging properties of date palm/polyvinyl chloride (PVC) composites.

作者信息

Boussehel Hamida, Guerira Belhi, Jawaid Mohammad, Fouad Hassan, Khiari Ramzi

机构信息

Laboratory of Mechanical Engineering LGM, University of Biskra, 07000, Biskra, Algeria.

Department of Mater Sciences, Faculty of Natural and Life Sciences, University of Biskra, 07000, Biskra, Algeria.

出版信息

Sci Rep. 2024 Sep 2;14(1):20384. doi: 10.1038/s41598-024-71489-x.

DOI:10.1038/s41598-024-71489-x
PMID:39223213
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11369266/
Abstract

The use of natural fibers has seen a significant rise in the composites sector, resulting in the creation of polymer composites with exceptional strength. These environmentally-friendly alternatives offer a compelling substitute for synthetic composites. This study explores the use of date palm waste as reinforcement for the fabrication of polyvinyl chloride (PVC) composites. A surface modification method was essential for improving the binding interaction between palm fibers and PVC composites. The two-hour benzoyl chloride treatment at 140 °C played a crucial role. The study examined the effects of hydrothermal aging on mechanical properties of composites, using various techniques such as surface morphology analysis, Fourier Transform Infrared spectroscopy, and Thermogravimetric Analysis, on composites made of untreated fibers and those treated with benzoyl chloride. Although the treatment of palm fiber-reinforced composites with benzoyl chloride improved their mechanical properties, it is crucial to note that hydrothermal aging reduced their tensile strength by 10%. Despite this, these composites prove to be well-suited for applications requiring moderate strength and stiffness in mild environmental conditions. These composites, while utilizing benzoyl chloride for surface treatment, still represent a more sustainable alternative to traditional synthetic composites by incorporating renewable date palm waste and enhancing mechanical properties, which potentially reduces overall environmental impact.

摘要

天然纤维在复合材料领域的应用显著增加,从而制造出具有卓越强度的聚合物复合材料。这些环保替代品为合成复合材料提供了极具吸引力的替代方案。本研究探索了将枣椰树废料用作增强材料来制造聚氯乙烯(PVC)复合材料。表面改性方法对于改善棕榈纤维与PVC复合材料之间的结合相互作用至关重要。在140°C下进行两小时的苯甲酰氯处理起到了关键作用。该研究使用表面形态分析、傅里叶变换红外光谱和热重分析等各种技术,研究了水热老化对由未处理纤维和经苯甲酰氯处理的纤维制成的复合材料力学性能的影响。尽管用苯甲酰氯处理棕榈纤维增强复合材料可改善其力学性能,但必须注意的是,水热老化使其拉伸强度降低了10%。尽管如此,这些复合材料被证明非常适合在温和环境条件下需要中等强度和刚度的应用。这些复合材料虽然使用苯甲酰氯进行表面处理,但通过纳入可再生的枣椰树废料并提高力学性能,仍然是传统合成复合材料更具可持续性的替代方案,这有可能降低整体环境影响。

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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c55/11369266/3f17ef67d43d/41598_2024_71489_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c55/11369266/1018c6cbbcb8/41598_2024_71489_Fig9_HTML.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c55/11369266/5dcfa32acb78/41598_2024_71489_Fig11_HTML.jpg

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苯甲酰氯处理的虎坚果纤维增强驱虫剂杂化复合材料的制备。
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