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化学气相沉积生长的MoS/Ag纳米颗粒杂化物中的增强拉曼散射

Enhanced Raman Scattering in CVD-Grown MoS/Ag Nanoparticle Hybrids.

作者信息

Maratos Dionysios M, Michail Antonios, Stamatelatos Alkeos, Grammatikopoulos Spyridon, Anestopoulos Dimitris, Tangoulis Vassilis, Papagelis Konstantinos, Parthenios John, Poulopoulos Panagiotis

机构信息

Department of Chemistry, University of Patras, 26504 Patras, Greece.

Department of Physics, University of Patras, 26504 Patras, Greece.

出版信息

Materials (Basel). 2024 Sep 6;17(17):4396. doi: 10.3390/ma17174396.

Abstract

Surface-Enhanced Raman Spectroscopy (SERS) is a powerful, non-destructive technique for enhancing molecular spectra, first discovered in 1974. This study investigates the enhancement of Raman signals from single- and few-layer molybdenum disulfide (MoS) when interacting with silver nanoparticles. We synthesized a MoS membrane primarily consisting of monolayers and bilayers through a wet chemical vapor deposition method using metal salts. The silver nanoparticles were either directly grown on the MoS membrane or placed beneath it. Raman measurements revealed a significant increase in signal intensity from the MoS membrane on the silver nanoparticles, attributed to localized surface plasmon resonances that facilitate SERS. Our results indicate that dichalcogenide/plasmonic systems have promising applications in the semiconductor industry.

摘要

表面增强拉曼光谱(SERS)是一种强大的无损技术,用于增强分子光谱,于1974年首次发现。本研究调查了单层和少层二硫化钼(MoS)与银纳米颗粒相互作用时拉曼信号的增强情况。我们通过使用金属盐的湿化学气相沉积法合成了主要由单层和双层组成的MoS膜。银纳米颗粒要么直接生长在MoS膜上,要么置于其下方。拉曼测量结果显示,银纳米颗粒上MoS膜的信号强度显著增加,这归因于促进SERS的局域表面等离子体共振。我们的结果表明,二硫族化物/等离子体系统在半导体行业具有广阔的应用前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c724/11396602/04d4d7156beb/materials-17-04396-g001.jpg

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