The Tuning of Strain in Layered Structure Oxide Cathodes for Lithium-Ion Batteries.

Layered structure oxides have emerged as highly promising cathode materials for lithium-ion batteries. In these cathode materials, volume variation related to anisotropic lattice strain during Li insertion/extraction, however, can induce critical structural instability and electrochemical degradation upon cycling. Despite extensive research efforts, solving the issues of lattice strain and mechanical fatigue remains a challenge. This perspective aims to establish the "structure-property relationship" between the degradation mechanism of the layered oxide cathode due to lattice strain and the structural evolution during cycling. By addressing these issues, we aim to guide the improvement of electrochemical performance, thereby facilitating the widespread adoption of these materials in future high-energy density lithium-ion batteries.