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不同乙二胺四乙酸(EDTA)用量对铈掺杂碲化铋(Ce-doped BiTe₃)花状形貌及热电性能的影响

The impact of varying EDTA dosage on the flower-like morphology and thermoelectric properties of Ce-doped BiTe₃.

作者信息

Wu Fang

机构信息

College of Computer and Artificial Intelligence, Henan Finance University, Zhengzhou, 450046, China.

出版信息

Sci Rep. 2024 Sep 19;14(1):21855. doi: 10.1038/s41598-024-72950-7.

Abstract

Thermoelectric materials have significant applications in energy utilization and environmental protection. The effect of different EDTA (ethylenediaminetetraacetic acid) dosages on the flower-like morphology and thermoelectric properties of Ce-doped BiTe nanoparticles were investigated. The Ce-doped BiTe nanoparticles were sucessfully prepared via the hydrothermal method, and the influence of EDTA dosage on the morphology, structure, and thermoelectric properties of the materials was analyzed. The experimental results showed that an appropriate amount of EDTA can promote the formation of a flower-like morphology in Ce-doped BiTe nanomaterials and enhance their thermoelectric properties. The ZT values of the x = 0.15 sample made by the better flower-like morphology of nanopowders are all around 1, which reach 1.15 at 398 K. This work demonstrates the synergistic effects of combining nanostructure engineering and chemical doping strategies for thermoelectric performance enhancement.

摘要

热电材料在能源利用和环境保护方面有重要应用。研究了不同乙二胺四乙酸(EDTA)用量对Ce掺杂BiTe纳米颗粒花状形貌和热电性能的影响。通过水热法成功制备了Ce掺杂BiTe纳米颗粒,并分析了EDTA用量对材料形貌、结构和热电性能的影响。实验结果表明,适量的EDTA可促进Ce掺杂BiTe纳米材料中花状形貌的形成并增强其热电性能。由具有较好花状形貌的纳米粉末制成的x = 0.15样品的ZT值均在1左右,在398 K时达到1.15。这项工作展示了结合纳米结构工程和化学掺杂策略以提高热电性能的协同效应。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4ce3/11413005/c6d67ca88957/41598_2024_72950_Fig1_HTML.jpg

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