四烯丙基硅烷的碘代重排反应与硅手性有机硅烷的合成。
Iodine Rearrangements of Tetraallylsilane and Synthesis of Silicon-Stereogenic Organosilanes.
机构信息
Department of Chemistry, Western Washington University, Bellingham, WA 98225, USA.
出版信息
Int J Mol Sci. 2024 Sep 17;25(18):9996. doi: 10.3390/ijms25189996.
Abstract
Tetraallylsilane can undergo either a mono or double rearrangement when treated with iodine (I). The extent of rearrangement depends on the equivalents of I used, where 1 equivalent gives high yields of mono-rearranged products and excess (e.g., 3 equivalents) causes double rearrangement to occur. This transformation can be applied to the synthesis of potentially valuable silicon-stereogenic organosilanes.
摘要
四烯丙基硅烷与碘（I）反应时可以发生单重或双重重排。重排的程度取决于所用的碘当量，其中 1 当量会产生高产率的单重排产物，而过量（例如 3 当量）则会导致双重重排发生。这种转化可用于合成具有潜在价值的硅手性有机硅烷。
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