Boeck Parker T, Veige Adam S
George & Josephine Butler Polymer Research Laboratory, Center for Macromolecular Sciences & Engineering, Department of Chemistry, University of Florida P.O. Box 117200 Gainesville FL 32611 USA.
Center for Catalysis, Department of Chemistry, University of Florida P.O. Box 117200 Gainesville FL 32611 USA
Chem Sci. 2024 Sep 4;15(39):16006-14. doi: 10.1039/d4sc04243c.
Cyclic polymers have applications across various fields, including material science, biomedicine, and inorganic chemistry. Cyclic polymers derived from alkyne monomers have expanded the application scope to include electronic materials and polyolefins. This review highlights recent advancements in the synthesis of cyclic polymers from both mono- and disubstituted alkynes. The aim is to provide a comprehensive overview of the synthetic methodologies and the application of cyclic polymers derived from alkynes. Additionally, this review will facilitate a comparative analysis of the advantages and limitations of various synthetic methods and describe opportunities for future development of novel catalytic systems to synthesize cyclic polymers from alkynes.
环状聚合物在包括材料科学、生物医学和无机化学在内的各个领域都有应用。由炔烃单体衍生而来的环状聚合物已将应用范围扩展到电子材料和聚烯烃领域。本综述重点介绍了由单取代和双取代炔烃合成环状聚合物的最新进展。目的是全面概述合成方法以及由炔烃衍生的环状聚合物的应用。此外，本综述将有助于对各种合成方法的优缺点进行比较分析，并描述未来开发新型催化体系以由炔烃合成环状聚合物的发展机会。
