Photocatalytic activity of self-heterojunctioned intermediate phases in HCl protonated and HNO deconjugated g-CN nanostructures.

This research involved the different acid-treatment conditions of graphitic carbon nitride and its modified nanostructures through thermal polycondensation of urea at various temperatures. X-ray diffraction patterns revealed that processing at a lower temperature than 500 °C resulted in melem and its derivatives, indicating incomplete transformation of urea to g-CN. However, treatment at higher temperatures and the HCl acid treatment led to the formation and expansion of g-CN networks, as evidenced by notable differences in peak intensities observed in their Fourier-transform infrared and Raman spectra. Scanning electron microscopy analysis illustrated a transition from the granular morphology of melamine to the layered structure characteristic of g-CN. The nanoparticle morphology observed in the HNO acid treatment sample was attributed to the deconjugation of nanosheets through the highly oxidative acid medium. The most suitable photocatalytic activity for Methylene Blue (MB) degradation under UV and visible light illumination was observed for the samples prepared at 550 °C and HCl post-processed nanostructures. It is proposed that the enhanced photocatalytic activity observed in these samples is most likely attributed to the reduced recombination of photogenerated charge carriers facilitated by heterojunctions formed between different intermediate phases. These findings highlight the potential of modified g-CN and its derivatives as promising photocatalytic materials for water purification applications.