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表面增强拉曼光谱在催化中的影响。

Impact of Surface Enhanced Raman Spectroscopy in Catalysis.

作者信息

Stefancu Andrei, Aizpurua Javier, Alessandri Ivano, Bald Ilko, Baumberg Jeremy J, Besteiro Lucas V, Christopher Phillip, Correa-Duarte Miguel, de Nijs Bart, Demetriadou Angela, Frontiera Renee R, Fukushima Tomohiro, Halas Naomi J, Jain Prashant K, Kim Zee Hwan, Kurouski Dmitry, Lange Holger, Li Jian-Feng, Liz-Marzán Luis M, Lucas Ivan T, Meixner Alfred J, Murakoshi Kei, Nordlander Peter, Peveler William J, Quesada-Cabrera Raul, Ringe Emilie, Schatz George C, Schlücker Sebastian, Schultz Zachary D, Tan Emily Xi, Tian Zhong-Qun, Wang Lingzhi, Weckhuysen Bert M, Xie Wei, Ling Xing Yi, Zhang Jinlong, Zhao Zhigang, Zhou Ru-Yu, Cortés Emiliano

机构信息

Nanoinstitute Munich, Faculty of Physics, Ludwig-Maximilians-Universität München, 80539 Munich, Germany.

IKERBASQUE, Basque Foundation for Science, 48011 Bilbao, Basque Country Spain.

出版信息

ACS Nano. 2024 Oct 29;18(43):29337-29379. doi: 10.1021/acsnano.4c06192. Epub 2024 Oct 14.

Abstract

Catalysis stands as an indispensable cornerstone of modern society, underpinning the production of over 80% of manufactured goods and driving over 90% of industrial chemical processes. As the demand for more efficient and sustainable processes grows, better catalysts are needed. Understanding the working principles of catalysts is key, and over the last 50 years, surface-enhanced Raman Spectroscopy (SERS) has become essential. Discovered in 1974, SERS has evolved into a mature and powerful analytical tool, transforming the way in which we detect molecules across disciplines. In catalysis, SERS has enabled insights into dynamic surface phenomena, facilitating the monitoring of the catalyst structure, adsorbate interactions, and reaction kinetics at very high spatial and temporal resolutions. This review explores the achievements as well as the future potential of SERS in the field of catalysis and energy conversion, thereby highlighting its role in advancing these critical areas of research.

摘要

催化是现代社会不可或缺的基石,支撑着80%以上制成品的生产,并推动着90%以上的工业化学过程。随着对更高效、可持续过程的需求不断增长,需要更好的催化剂。了解催化剂的工作原理是关键,在过去50年里,表面增强拉曼光谱(SERS)变得至关重要。SERS于1974年被发现,已发展成为一种成熟且强大的分析工具,改变了我们跨学科检测分子的方式。在催化领域,SERS能够洞察动态表面现象,有助于在非常高的空间和时间分辨率下监测催化剂结构、吸附质相互作用和反应动力学。本综述探讨了SERS在催化和能量转换领域的成就以及未来潜力,从而突出其在推动这些关键研究领域方面的作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/70fa/11526435/611e56ded1b1/nn4c06192_0001.jpg

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