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量子锥——一种具有沿高度和时间分布的色散光谱的纳米光源。

Quantum Cone-A Nano-Source of Light with Dispersive Spectrum Distributed along Height and in Time.

作者信息

Medvids Arturs, Ščajev Patrik, Hara Kazuhiko

机构信息

Insitute of Technical Physics, Riga Technical University, Paula Valdena 3/7, 1048 Riga, Latvia.

Institute of Photonics and Nanotechnology, Faculty of Physics, Vilnius University, Saulėtekio Ave. 3, 10257 Vilnius, Lithuania.

出版信息

Nanomaterials (Basel). 2024 Sep 30;14(19):1580. doi: 10.3390/nano14191580.

Abstract

We study a quantum cone, a novel structure composed of multiple quantum dots with gradually decreasing diameters from the base to the top. The dot distribution leads to a dispersive radiated spectrum. The blue edge of the spectrum is determined by the quantum confinement of excitons on top of the cones, while the red edge is determined by the bandgap of a semiconductor. We observe the kinetics of photoluminescence by obeying the stretch-exponential law from quantum cones formed on the surface of diamond-like carbon (DLC). They are explained by an increase in the lifetime of excitons along the height of the cone from the top to the base of the cone and an increasing concentration of excitons at the base due to their drift in the quasi-built-in electric field of the quantum cone. The possible visualization of the quantum cone tops of DLC using irradiation by a UV light source is shown. A quantum cone is an innovative nano-source of light because it substitutes for two elements in a conventional spectrometer: a source of light and a dispersive element-an ultrafast monochromator. These features enable the building of a nano-spectrometer to measure the absorbance spectra of virus and molecule particles.

摘要

我们研究了一种量子锥,它是一种由多个量子点组成的新型结构,其直径从底部到顶部逐渐减小。这种量子点分布导致了色散辐射光谱。光谱的蓝边由锥体顶部激子的量子限制决定,而红边则由半导体的带隙决定。我们通过遵循类金刚石碳(DLC)表面形成的量子锥的拉伸指数定律来观察光致发光动力学。这可以通过从锥体顶部到锥体底部激子寿命的增加以及由于激子在量子锥的准内建电场中的漂移导致锥体底部激子浓度增加来解释。展示了使用紫外光源照射对DLC量子锥顶部进行可视化的可能性。量子锥是一种创新的纳米光源,因为它替代了传统光谱仪中的两个元件:光源和色散元件——超快单色仪。这些特性使得构建一种纳米光谱仪来测量病毒和分子颗粒的吸收光谱成为可能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f958/11478285/ab812592fd51/nanomaterials-14-01580-g001.jpg

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