Napolitano Francesco, Papa Ilaria, Cimino Francesca, Lopresto Valentina, Russo Pietro
Institute of Polymers, Composites and Biomaterials, National Research Council, Via Campi Flegrei 34, 80078 Pozzuoli, Italy.
Department of Chemical, Materials and Production Engineering, University of Naples "Federico II", P.le Tecchio 80, 80125 Naples, Italy.
Polymers (Basel). 2024 Sep 24;16(19):2682. doi: 10.3390/polym16192682.
Additive manufacturing processes allow for precise and efficient production, but it is estimated that one-third of the materials used results in waste. Further improvement in a sustainable perspective could come from the ability to manage these scraps and from the exploration of different routes for recovery and reuse. The Selective Laser Sintering process is particularly sensitive to this issue due to the waste ratio which can reach a very high quantity of not-sintered virgin powders. In this research study, recovered PA12 powders, preliminarily characterized through thermal and mechanical analysis, were mixed with 15% basalt powder to improve their aspect and thermomechanical resistance. The influence of basalt powder (BP) on mechanical properties as well as on the thermal stability of polyamide12 (PA12) powder composites was investigated. A study conducted on mechanical properties showed that polymeric composites' stiffness and hardness were influenced by adding filler, thus improving mechanical parameters. On the other hand, the application of thermogravimetric analysis allowed us to determine the composite's thermal stability. The objective is to obtain a recovered fully biobased material that could be used to substitute the petroleum-derived polymeric ones currently employed in the production of interiors and shells in the automotive sector.
增材制造工艺能够实现精确且高效的生产,但据估计,所使用材料中有三分之一会产生废料。从可持续发展的角度来看,进一步的改进可源于对这些废料的管理能力以及对不同回收和再利用途径的探索。选择性激光烧结工艺对这个问题尤为敏感,因为废料比例可能会达到非常大量的未烧结原始粉末。在本研究中,通过热分析和力学分析初步表征的回收PA12粉末与15%的玄武岩粉末混合,以改善其外观和热机械抗性。研究了玄武岩粉末(BP)对聚酰胺12(PA12)粉末复合材料力学性能以及热稳定性的影响。一项关于力学性能的研究表明,添加填料会影响聚合物复合材料的刚度和硬度,从而改善力学参数。另一方面,热重分析的应用使我们能够确定复合材料的热稳定性。目标是获得一种回收的全生物基材料,可用于替代目前汽车行业内饰和外壳生产中使用的石油衍生聚合物材料。