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使用水性环氧丙烯酸酯树脂改性乳化沥青(WEREA)制备高性能沥青混合料

Fabrication of High-Performance Asphalt Mixture Using Waterborne Epoxy-Acrylate Resin Modified Emulsified Asphalt (WEREA).

作者信息

Chen Dongwei, Wu Hao, Chen Xiaobao, Zhan Yiqun, Wada Surajo Abubakar

机构信息

School of Civil Engineering, Central South University, 22 South Shaoshan Rd., Changsha 410075, China.

Department of Civil Engineering, Ahmadu Bello University, Zaria 810107, Nigeria.

出版信息

Polymers (Basel). 2024 Sep 27;16(19):2743. doi: 10.3390/polym16192743.

Abstract

Existing research shows that using waterborne epoxy resin (WER) instead of emulsified asphalt as the binder for cold mix asphalt (CMA) can enhance the rutting resistance, high-temperature performance, fracture performance, and early performance of CMA. In order to eliminate the potential drawbacks such as insufficient strength and low-temperature performance of CMA during application, a novel method was proposed in this study for the preparation of waterborne epoxy-acrylate resin (WER), specifically tailored to modify emulsified asphalt, resulting in waterborne epoxy-acrylate resin emulsified asphalt (WEREA). The modification effect of WER on emulsified asphalt was evaluated through rheological tests and direct tensile tests. A modified design method based on the conventional Marshall design method was proposed to determine the optimal mix proportions, including the key parameters of specimen compaction and curing. The results revealed that the incorporation of WER led to a substantial improvement in the complex shear modulus and a concurrent decrease in the phase angle. When the temperature exceeded 60 °C, the phase angle exhibited a diminishing trend, indicative of a reduced viscosity as temperatures escalated. As the WER content increased, a decrease in the direct tensile strain rate was observed, accompanied by a substantial elevation in direct tensile strength. At various stress levels, the shear strain of WEREA decreases with increased content of WER, indicating that the incorporation of WER can enhance the hardness of emulsified asphalt and improve its deformation resistance. The results from MSCR tests indicate that WER could significantly improve the elasticity and hardness of emulsified asphalt, transitioning it from a viscoelastic material to an elastic material, thereby improving its deformation resistance, resistance to rutting, and high-temperature performance. The results of fatigue life are consistent with those of the amplitude sweep, both reflecting the improvement of resistance to deformation of emulsified asphalt by WER. This indicates that WER has a significant improving effect on the fatigue resistance of emulsified asphalt. Furthermore, the Marshall design tests further confirmed the advantages of WEREA in asphalt mixtures. The optimal preparation for the WEREA mixture was proposed as follows: double-sided compaction for 50 times each, aging at 60 °C for 48 h, optimal moisture content of 5.14%, cement content of 2.5%, and emulsion content of 8.4%. The optimal mix proportions identified through these tests yielded asphalt mixtures with significantly improved stability, reduced flow value, and enhanced rutting resistance compared to the hot-mix asphalt mixture (HMA) of AC-16. These findings suggest that WEREA has the potential to significantly enhance the durability and longevity of asphalt pavements. For future applications, it can be explored for use in producing cold recycled asphalt mixtures. In addition to designing the WEREA mixture according to AC-16 gradation, consideration can also be given to using a gradation with a smaller nominal maximum aggregate size for the application in the surface layer or ultra-thin wearing course.

摘要

现有研究表明,使用水性环氧树脂(WER)代替乳化沥青作为冷拌沥青(CMA)的粘结剂,可以提高CMA的抗车辙性能、高温性能、断裂性能和早期性能。为了消除CMA在应用过程中强度不足和低温性能等潜在缺点,本研究提出了一种制备水性环氧丙烯酸酯树脂(WER)的新方法,专门用于改性乳化沥青,从而得到水性环氧丙烯酸酯树脂乳化沥青(WEREA)。通过流变试验和直接拉伸试验评估了WER对乳化沥青的改性效果。提出了一种基于传统马歇尔设计方法的改性设计方法,以确定最佳配合比,包括试件压实和养护的关键参数。结果表明,加入WER导致复数剪切模量显著提高,相位角同时减小。当温度超过60℃时,相位角呈下降趋势,表明随着温度升高粘度降低。随着WER含量的增加,直接拉伸应变率降低,同时直接拉伸强度大幅提高。在不同应力水平下,WEREA的剪切应变随WER含量的增加而减小,表明加入WER可以提高乳化沥青的硬度并改善其抗变形能力。MSCR试验结果表明,WER可以显著提高乳化沥青的弹性和硬度,使其从粘弹性材料转变为弹性材料,从而提高其抗变形能力、抗车辙能力和高温性能。疲劳寿命结果与振幅扫描结果一致,均反映了WER对乳化沥青抗变形能力的改善。这表明WER对乳化沥青的疲劳抗性有显著的改善作用。此外,马歇尔设计试验进一步证实了WEREA在沥青混合料中的优势。提出WEREA混合料的最佳制备方法如下:双面各压实50次,在60℃下老化48h,最佳含水量为5.14%,水泥含量为2.5%,乳液含量为8.4%。通过这些试验确定的最佳配合比所得到的沥青混合料与AC - 16热拌沥青混合料(HMA)相比,稳定性显著提高,流值降低,抗车辙能力增强。这些发现表明,WEREA有潜力显著提高沥青路面的耐久性和使用寿命。在未来的应用中,可以探索将其用于生产冷再生沥青混合料。除了按照AC - 16级配设计WEREA混合料外,还可以考虑使用公称最大集料粒径较小的级配用于表面层或超薄磨耗层的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82b7/11478679/f22737475608/polymers-16-02743-g001.jpg

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