Nature of the lunar far-side samples returned by the Chang'E-6 mission.

The Chang'E-6 (CE-6) mission successfully achieved return of the first samples from the far side of the Moon. The sampling site of CE-6 is located in the South Pole-Aitken (SPA) basin-the largest, deepest and oldest impact basin on the Moon. The 1935.3 g of CE-6 lunar samples exhibit distinct characteristics compared with previous lunar samples. This study analyses the physical, mineralogical, petrographic and geochemical properties of CE-6 lunar scooped samples. The CE-6 soil has a significantly lower bulk density (0.983 g/cm) and true density (3.035 g/cm) than the Chang'E-5 (CE-5) samples. The grain size of the CE-6 soil exhibits a bimodal distribution, indicating a mixture of different compositions. Mineralogically, the CE-6 soil consists of 32.6% plagioclase (anorthite and bytownite), 19.7% augite, 10% pigeonite and 3.6% orthopyroxene, and with low content of olivine (0.5%) but high content of amorphous glass (29.4%). Geochemically, the bulk composition of CE-6 soil is rich in AlO (14%) and CaO (12%) but low in FeO (17%), and trace elements of CE-6 soil such as K (∼630 ppm), U (0.26 ppm), Th (0.92 ppm) and rare-earth elements are significantly lower than those of the lunar soils within the Procellarum KREEP Terrane. The local basalts are characterized by low-Ti (TiO, 5.08%), low-Al (AlO 9.85%) and low-K (∼830 ppm), features suggesting that the CE-6 soil is a mixture of local basalts and non-basaltic ejecta. The returned CE-6 sample contains diverse lithic fragments, including local mare basalt, breccia, agglutinate, glasses and leucocrate. These local mare basalts document the volcanic history of the lunar far side, while the non-basaltic fragments may offer critical insights into the lunar highland crust, SPA impact melts and potentially the deep lunar mantle, making these samples highly significant for scientific research.