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从自然蓝图中汲取的环状碳酸酯合成学习策略。

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis.

作者信息

Saccullo Erika, Patamia Vincenzo, Zagni Chiara, Rescifina Antonio, Floresta Giuseppe

机构信息

Department of Drug and Health Sciences, University of Catania, Viale Andrea Doria 6, 95125, Catania, Italy.

Department of Biomedical and Biotechnological Sciences (Biometec), University of Catania, Via Santa Sofia 97, 95123, Catania, Italy.

出版信息

ChemSusChem. 2025 Mar 15;18(6):e202402061. doi: 10.1002/cssc.202402061. Epub 2024 Nov 27.

Abstract

Nature is a remarkable source of inspiration for developing sustainable and eco-friendly synthetic procedures. In recent years, the synthesis of cyclic carbonates has garnered significant attention due to their versatile applications in various fields, including materials science, pharmaceuticals, and green chemistry. Drawing inspiration from nature, researchers have explored innovative synthetic routes that mimic biological processes to produce cyclic carbonates efficiently and sustainably. This article reviews nature-inspired synthetic procedures for cyclic carbonate formation, highlighting the key strategies and principles employed. Through biomimicry, researchers aim to harness the efficiency and selectivity observed in biological systems to develop greener and more sustainable methods for cyclic carbonates synthesis. Integrating bio-inspired strategies offers opportunities for improving synthetic efficiency and contributes to reducing the environmental impact associated with traditional chemical processes. This review underscores the potential of nature-inspired approaches in advancing the field of cyclic carbonate synthesis toward more sustainable and environmentally benign practices, focusing on recent literature.

摘要

自然是开发可持续且环保的合成方法的非凡灵感来源。近年来,环状碳酸酯的合成因其在材料科学、制药和绿色化学等各个领域的广泛应用而备受关注。受自然启发,研究人员探索了模仿生物过程的创新合成路线,以高效且可持续地生产环状碳酸酯。本文综述了受自然启发的环状碳酸酯形成的合成方法,突出了所采用的关键策略和原则。通过仿生学,研究人员旨在利用在生物系统中观察到的效率和选择性,开发更绿色、更可持续的环状碳酸酯合成方法。整合受生物启发的策略为提高合成效率提供了机会,并有助于减少与传统化学过程相关的环境影响。本综述强调了受自然启发的方法在推动环状碳酸酯合成领域朝着更可持续和环境友好的实践发展方面的潜力,重点关注近期文献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7623/11911979/fc1902c5e4f1/CSSC-18-e202402061-g023.jpg

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